This disclosure relates to a continuous solution polymerization process wherein production rate is increased. Process solvent, ethylene, optional comonomers, optional hydrogen and a single site catalyst formulation are injected into a first reactor forming a first ethylene interpolymer. Process solvent, ethylene, optional comonomers, optional hydrogen and a heterogeneous catalyst formulation are injected into a second reactor forming a second ethylene interpolymer. The first and second reactors may be configured in series or parallel modes of operation. Optionally, a third ethylene interpolymer is formed in an optional third reactor, wherein an optional heterogeneous catalyst formulation may be employed. In a solution phase, the first, second and optional third ethylene interpolymers are combined, the catalyst is deactivated, the solution is passivated and following a phase separation process an ethylene interpolymer product is recovered.

Solution polymerization process

Investigation of electrostatic charge distribution in gas–solid fluidized beds

Computational fluid dynamics and electrostatic modeling of polymerization fluidized-bed reactors

A method of vehicle monitoring includes monitoring one or more vehicle safety systems while a vehicle is in operation to detect an unsafe condition. The method also includes sending an alert to a handheld device if an unsafe condition is detected.

Vehicle system passive notification using remote device

Downhole systems and methods including tags configured to provide distinguishable identifiers are set for selective release to a subsurface location. Sources/sensors in the wellbore are activated to detect the tags at a subsurface location, and signal data associated with the detected tags is conveyed to the surface.

Subsurface tagging system with wired tubulars

Embodiments of the present invention relate to measuring and controlling static in a gas phase reactor polymerization. In particular, embodiments relate to monitoring carryover static in an entrainment zone during gas phase polymerization to determine the onset of reactor discontinuity events such as chunking and sheeting. Embodiments also relate to monitoring carryover static to determine the need for effective additions of continuity additives that minimize reactor static activity and thereby preventing discontinuity events.

Method for controlling sheeting in gas phase reactors

A continuous gas fluidized bed polymerization process for the production of a polymer from a monomer including continuously passing a gaseous stream comprising the monomer through a fluidized bed reactor in the presence of a catalyst under reactive conditions; withdrawing a polymeric product and a stream comprising unreacted monomer gases; cooling said stream comprising unreacted monomer gases to form a mixture comprising a gas phase and a liquid phase and reintroducing said mixture into said reactor with sufficient additional monomer to replace that monomer polymerized and withdrawn as the product, wherein said liquid phase is vaporized, and wherein the stream comprises an induced condensing agent selected from the group consisting of alkanes, cycloalkanes, and mixtures thereof, the induced condensing agent having a normal boiling point less than 25° C.

Condensing mode operation of gas-phase polymerization reactor

In some embodiments, a method including the steps of: during a polymerization reaction producing a polymer resin in a fluid bed reactor, measuring reaction parameters including at least reactor temperature, at least one property of the resin, and amount of at least one condensable diluent gas in the reactor; determining from at least one measured resin property using a predetermined correlation, a dry melt initiation temperature value for a dry version of the polymer resin; and during the reaction, using a melt initiation temperature depression model to determine in on-line fashion a reduced melt initiation temperature for the resin (e.g., a temperature at which the resin is expected to begin to melt) in the presence of the at least one condensable diluent gas in the reactor.

Methods for on-line determination of degree of resin stickiness using a model for depression of melt initiation temperature

The invention relates to a method for evaluating the condition of a fluidized bed reactor by examining the condition of the reactor wall Specifically, the invention relates to a method for measuring static in the reactor using a static probe that is located at the distributor plate and comprises a distributor plate cap The invention also relates to methods of determining a static level using a radio frequency (rf) The static measurements are provided to indicate or predict major continuity disturbances in the fluidized bed gas phase reactor

Static measurement and detection in a gas phase polyethylene reactor

Embodiments of the present invention relate to operating at least one gas-phase reactor at or near maximum production rates and to measuring and controlling polymer stickiness in a gas phase reactor polymerization. In particular, embodiments relate to monitoring acoustic emissions in a reactor during gas phase polymerization to determine the onset of reactor stickiness and possibly discontinuity events such as chunking and sheeting resulting from that stickiness. Embodiments also relate to monitoring acoustic emissions to determine the need for effective control of parameters that minimize reactor stickiness and thereby preventing discontinuity events. The emissions are processed by arithmetic averaging.

Method for operating a gas-phase reactor at or near maximum production rates while controlling polymer stickiness

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