About: sec-Butyl acetate is a research topic. Over the lifetime, 105 publications have been published within this topic receiving 447 citations. The topic is also known as: 2-butyl acetate & s-butyl acetate.
TL;DR: In this paper, the authors derived relative rate constants for the reaction of the hydroxyl radical with these organics using a flash photolysis-resonance fluorescence technique.
TL;DR: In this article, the catalytic activity for the preparation of sec-butanol via the transesterification of Sec-butyl acetate (SBAC) with methanol was investigated.
TL;DR: In this paper, a material-conserving analytical solubility measurement technique, with in-line reversed HPLC separation protocol, was employed to measure the mole fraction of lovastatin.
Abstract: A material-conserving analytical solubility measurement technique, with in-line reversed HPLC separation protocol, was employed to measure the mole fraction solubility of lovastatin in methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, sec-butyl acetate, tert-butyl acetate, acetone, and 2-butanone between (285 and 313) K. We examine three methods for the estimation of the ideal solubility of lovastatin by using different approximations for the difference between the heat capacity of the solid and the liquid at the melting point ΔCP = CPL − CPS. The solubility data were combined with calculated ideal solubility data to determine the activity coefficients of lovastatin which are then fitted to a van’t Hoff form equation to obtain estimated values of the partial molar enthalpy of mixing, ΔmixH∞, and partial molar entropy of mixing, ΔmixS∞, respectively. Thermodynamic consistency was confirmed when ΔCP = CPL − CPS was used in the ideal solubility calculation.
TL;DR: In this article, the binary and ternary VLE data were measured for the binary systems sec-butyl alcohol+dimethyl sulfoxide (DMSO), sec- butyl acetate+ DMSO at 101.3 kPa.
TL;DR: In this paper, the NRTL and UNIQUAC models were applied to fit the experimental data for the ternary system and the binary interaction parameters obtained from both models were successfully correlated with the equilibrium compositions.