Master equation

Abstract: We study coupled irreversible processes. For linear or linearized kinetics with microreversibility, $\dot{x}=Kx$, the kinetic operator $K$ is symmetric in the entropic inner product. This form of Onsager's reciprocal relations implies that the shift in time, $\exp (Kt)$, is also a symmetric operator. This generates the reciprocity relations between the kinetic curves. For example, for the Master equation, if we start the process from the $i$th pure state and measure the probability $p_j(t)$ of the $j$th state ($j eq i$), and, similarly, measure $p_i(t)$ for the process, which starts at the $j$th pure state, then the ratio of these two probabilities $p_j(t)/p_i(t)$ is constant in time and coincides with the ratio of the equilibrium probabilities. We study similar and more general reciprocal relations between the kinetic curves. The experimental evidence provided as an example is from the reversible water gas shift reaction over iron oxide catalyst. The experimental data are obtained using Temporal Analysis of Products (TAP) pulse-response studies. These offer excellent confirmation within the experimental error.

Abstract: Instituto de F´isica y Matema´ticas, Universidad Michoacana de San Nicol´as de Hidalgo,Apdo. Postal 2-82, C.P. 58040, Morelia, Michoac´an, MexicoUsing Lewis-Riesenfeld theory, we derive an exact non-adiabatic master equation describing thetime evolution of the QED Schwinger pair production rate for a general time-varying electric field.This equation can be written equivalently as a first-order matrix equation, as a Vlasov type integralequation, or as a third-order differential equation. In the last version it relates to the KdV equation,which allows us to construct an exact solution using the well-known one-soliton solution to thatequation. The case of time-like delta function pulse fields is also shortly considered. We comparewith previous approaches to the purely time-dependent field case.

Abstract: A quantum system $${\mathcal S}$$ undergoing continuous time measurement is usually described by a jump-diffusion stochastic differential equation. Such an equation is called a quantum filtering equation (or quantum stochastic master equation) and its solution is called a quantum filter (or quantum trajectory). This solution describes the evolution of the state of $${\mathcal S}$$ . In the context of quantum non demolition measurement, we investigate the large time behavior of this solution. It is rigorously shown that, for large time, this solution behaves as if a direct Von Neumann measurement has been performed at time 0. In particular the solution converges to a random pure state which can be directly linked to the wave packet reduction postulate. Using the theory of Girsanov transformation, we obtain the explicit rate of convergence towards this random state. The problem of state estimation (used in experiment) is also investigated.

Abstract: A compact and analytical model for silicon single-electron transistors (SETs) considering the discrete quantum energy levels and the parabolic tunneling barriers is proposed. The model is based on a steady-state master equation that considers only the three most probable states derived from ground level and the first excited level for each number of electrons in the dot to reduce the complexity while accounting for the quantum-level spacing and multiple peaks in Coulomb oscillation. Negative differential conductance (NDC) characteristics and aperiodic Coulomb oscillations due to nonuniform quantum-level spacings can be reproduced in this model. The model was compared with measurements, and good agreement was obtained. Simulations of some basic circuits that utilize NDC are successfully carried out by applying our model to the HSPICE circuit simulation. Our model can provide suitable environments for designing CMOS-combined room-temperature-operating highly functional SET circuits.