Since the first application of the surface plasmon resonance (SPR) phenomenon for sensing almost two decades ago, this method has made great strides both in terms of instrumentation development and applications. SPR sensor technology has been commercialized and SPR biosensors have become a central tool for characterizing and quantifying biomolecular interactions. This paper attempts to review the major developments in SPR technology. Main application areas are outlined and examples of applications of SPR sensor technology are presented. Future prospects of SPR sensor technology are discussed.

Surface plasmon resonance sensors: review

The rigorous coupled-wave analysis technique for describing the diffraction of electromagnetic waves by periodic grating structures is reviewed. Formulations for a stable and efficient numerical implementation of the analysis technique are presented for one-dimensional binary gratings for both TE and TM polarization and for the general case of conical diffraction. It is shown that by exploitation of the symmetry of the diffraction problem a very efficient formulation, with up to an order-of-magnitude improvement in the numerical efficiency, is produced. The rigorous coupled-wave analysis is shown to be inherently stable. The sources of potential numerical problems associated with underflow and overflow, inherent in digital calculations, are presented. A formulation that anticipates and preempts these instability problems is presented. The calculated diffraction efficiencies for dielectric gratings are shown to converge to the correct value with an increasing number of space harmonics over a wide range of parameters, including very deep gratings. The effect of the number of harmonics on the convergence of the diffraction efficiencies is investigated. More field harmonics are shown to be required for the convergence of gratings with larger grating periods, deeper gratings, TM polarization, and conical diffraction.

http://circuit.ucsd.edu/~zhaowei/ECE212C/notes/Lecture6_reading_materials.pdf

Formulation for stable and efficient implementation of the rigorous coupled-wave analysis of binary gratings

An enhanced, numerically stable transmittance matrix approach is developed and is applied to the implementation of the rigorous coupled-wave analysis for surface-relief and multilevel gratings. The enhanced approach is shown to produce numerically stable results for excessively deep multilevel surface-relief dielectric gratings. The nature of the numerical instability for the classic transmission matrix approach in the presence of evanescent fields is determined. The finite precision of the numerical representation on digital computers results in insufficient accuracy in numerically representing the elements produced by inverting an ill-conditioned transmission matrix. These inaccuracies will result in numerical instability in the calculations for successive field matching between the layers. The new technique that we present anticipates and preempts these potential numerical problems. In addition to the full-solution approach whereby all the reflected and the transmitted amplitudes are calculated, a simpler, more efficient formulation is proposed for cases in which only the reflected amplitudes (or the transmitted amplitudes) are required. Incorporating this enhanced approach into the implementation of the rigorous coupled-wave analysis, we obtain numerically stable and convergent results for excessively deep (50 wavelengths), 16-level, asymmetric binary gratings. Calculated results are presented for both TE and TM polarization and for conical diffraction.

Stable implementation of the rigorous coupled-wave analysis for surface-relief gratings: enhanced transmittance matrix approach

Anti-reflective coatings (ARCs) have evolved into highly effective reflectance and glare reducing components for various optical and opto-electrical equipments. Extensive research in optical and biological reflectance minimization as well as the emergence of nanotechnology over the years has contributed to the enhancement of ARCs in a major way. In this study the prime objective is to give a comprehensive idea of the ARCs right from their inception, as they were originally conceptualized by the pioneers and lay down the basic concepts and strategies adopted to minimize reflectance. The different types of ARCs are also described in greater detail and the state-of-the-art fabrication techniques have been fully illustrated. The inspiration that ARCs derive from nature (‘biomimetics’) has been an area of major research and is discussed at length. The various materials that have been reportedly used in fabricating the ARCs have also been brought into sharp focus. An account of application of ARCs on solar cells and modules, contemporary research and associated challenges are presented in the end to facilitate a universal understanding of the ARCs and encourage future research.

Anti-reflective coatings: A critical, in-depth review

We present an ultrabroadband thin-film infrared absorber made of sawtoothed anisotropic metamaterial. Absorptivity of higher than 95% at normal incidence is supported in a wide range of frequencies, where the full absorption width at half-maximum is about 86%. Such property is retained well at a very wide range of incident angles too. Light of shorter wavelengths are harvested at upper parts of the sawteeth of smaller widths, while light of longer wavelengths are trapped at lower parts of larger tooth widths. This phenomenon is explained by the slowlight modes in anisotropic metamaterial waveguide. Our study can be applied in the field of designing photovoltaic devices and thermal emitters.

/pdf/ultrabroadband-light-absorption-by-a-sawtooth-anisotropic-1dp1emuh97.pdf

Ultrabroadband light absorption by a sawtooth anisotropic metamaterial slab

A rigorous coupled-wave analysis for metallic surface-relief gratings is presented. This approach allows an arbitrary complex permittivity to be used for the material and thus avoids the infinite conductivity (perfect-conductor) approximation. Both TE and TM polarizations and arbitrary angles of incidence are treated. Diffraction characteristics for rectangular-groove gold gratings with equal groove and ridge widths are presented for free-space wavelengths of 0.5, 1.0 and 10.0 μm for all diffracted orders as a function of period, groove depth, polarization, and angle of incidence. Results include the following: (1) TM-polarization diffraction characteristics vary more rapidly than do those for TE polarization, (2) 95% first-order diffraction efficiency occurs for TM polarization at 10.0 μm, (3) 50% absorption of incident power occurs at 0.5 μm, and (5) the perfect-conductor approximation is not valid for TM polarization at any of the wavelengths and is not valid for TE polarization at 0.5 μm.

Rigorous coupled-wave analysis of metallic surface-relief gratings

Using rigorous coupled-wave analysis, high spatial-frequency rectangular-groove surface-relief phase gratings are shown to be capable of exhibiting zero reflectivity. Thus these corrugated surfaces may act as antireflection coatings in a variety of applications. The diffraction characteristics of rectangular-groove surface-relief gratings are presented for several ratios of incident wavelength to grating period as a function of filling factor, groove depth, angle of incidence, and polarization. The conditions for zero reflectivity are identified. Results are compared with single-homogeneous-layer approximate theory results. In the limit of long wavelengths for an electromagnetic wave in a dielectric of refractive index n1 normally incident on a dielectric of index n2, it is determined that for antireflection behavior, the grating groove depth should be λ/4(n1n2)1/2 and the filling factor should be n1/(n1 + n2) or n2/(n1 + n2) for the electric field perpendicular or parallel to the grating vector, respectively. The spectral and angular responses of these gratings are like those of single-homogeneous-layer antireflection coatings. These gratings also exhibit birefringent retardation.

Zero-reflectivity high spatial-frequency rectangular-groove dielectric surface-relief gratings.

The required thickness and complex refractive index of single homogeneous layers on lossy substrates to produce zero reflectivity are calculated by a rigorous impedance matching approach. The analysis is applicable to both TE and TM polarization and to any angle of incidence. The filling factor and groove depth of a rectangular-groove grating, equivalent to a single homogeneous lossy layer in the long-wavelength limit, are calculated. The method reduces to that previously found for dielectric surface-relief gratings in the limit of no losses. The antireflection behavior of the gratings is verified using the rigorous (without approximations) coupled-wave analysis of metallic surface-relief grating diffraction. It is shown that multiple zero-reflectivity solutions exist for both TE and TM polarizations and for any angle of incidence for an arbitrary complex-refractive-index substrate. Example zero-reflectivity gold gratings for incident free space wavelengths from 0.44 to 12.0 μm are presented.

Zero-reflectivity homogeneous layers and high spatial-frequency surface-relief gratings on lossy materials

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Rigorous coupled-wave analysis of metallic surface-relief gratings

Zero-reflectivity high spatial-frequency rectangular-groove dielectric surface-relief gratings.

Zero-reflectivity homogeneous layers and high spatial-frequency surface-relief gratings on lossy materials