The invention provides a nitrogen tetroxide waste solution treatment device and a waste solution treatment method thereof. According to the device, a storage tank (1) storing nitrogen tetroxide is pressurized with nitrogen firstly, nitrogen tetroxide is extruded out and is atomized by a high-efficiency mixer (6) when entering an absorbing tower (4), meanwhile, water in a water tank (3) is conveyed by a centrifuge pump (5) to the top of the absorbing tower (4) to be sprayed, the water and nitrogen tetroxide make fully contact in the absorbing tower (4) to react to produce nitric acid and nitric oxide gas, nitric oxide gas is continuously oxidized into nitrogen dioxide with excessive oxygen under the action of an air blower (2), and nitrogen dioxide is circulated to be absorbed by the water until completely transformed into nitric acid. The nitrogen tetroxide waste solution treatment device is simple in structure and safe, simple and convenient to operate and causes no pollution to the environment, the tail gas concentration of an exhaust port (7) is lower than 1.5 ppm all the time in the treatment process, and the absorbing efficiency can reach 99.5%.

Nitrogen tetroxide waste solution treatment device and waste solution treatment method thereof

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Nitrogen tetroxide waste solution treatment device and waste solution treatment method thereof