Topic
Voltammetry
About: Voltammetry is a research topic. Over the lifetime, 9269 publications have been published within this topic receiving 233228 citations. The topic is also known as: voltamperometry.
Papers published on a yearly basis
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Papers
TL;DR: In this article, the equation of the linear potential sweep voltammogram is derived for any degree of reversibility of the electrochemical reaction for the following methods: surface voltammetry when both the oxidized and the reduced forms are strongly adsorbed, and a Langmuir isotherm is obeyed, thin layer voltamometry, and linear potential sweeping coulometry.
6,623 citations
TL;DR: In this paper, the effects of a strong adsorption of the depolarizer and/or of the product of the electrochemical reaction on the currents obtained in polarography and in linear potential sweep voltammetry (l.p.s.v.) are considered.
1,689 citations
TL;DR: In this article, the properties of Li+ ion insertion in nanoporous TiO2 (anatase) electrodes were studied by voltammetry and linear and cyclic potential scans were recorded as a function of electrolyte con...
Abstract: Electrochemical properties of Li+ ion insertion in nanoporous TiO2 (anatase) electrodes were studied by voltammetry. Linear and cyclic potential scans were recorded as a function of electrolyte con ...
1,438 citations
TL;DR: In this paper, the authors studied the effect of CO2 adsorption strength on the production of CO at the Cu electrode in aqueous inorganic electrolytes and compared the mechanism of the Fishcher-Tropsch reaction.
Abstract: Electroreduction of CO2 at Cu in aqueous inorganic electrolytes was studied by means of voltammetric, coulometric and chronopotentiometric measurements. CO, CH4, C2H4, EtOH and PrnOH are produced at ambient temperatures. Formation of CO predominates at less negative potentials (more positive than –1.2 V vs. NHE); hydrocarbons and alcohols are favourably produced below –1.3 V vs. NHE, where the Faradaic efficiency of CO drops. CO, formed as an intermediate from CO2, is adsorbed on the Cu electrode, interfering with cathodic hydrogen formation. The adsorption strength of CO on Cu is very weak as compared with that on Pt. Adsorbed CO is reduced to Hydrocarbons and alcohols at more negative potentials. The product distribution from CO2 depends strongly upon the electrolytes employed. Formation of C2H4 and alcohols is favoured in KCl, K2SO4, KClO4 and dilute HCO–3 solutions, whereas CH4 is preferentially produced in relatively concentrated HCO–3 and phosphate solutions. The product selectivity depends upon availability of hydrogen or protons on the surface, which is controlled by pH at the electrode. The pH at the electrode is greatly affected by the electrolyte, since OH– is released in the electrode reactions. The production of hydrocarbons and alcohols is discussed in comparison with the mechanism of the Fishcher–Tropsch reaction.
1,416 citations
TL;DR: In this paper, a critical review of conversion constants amongst various reference electrodes reported in the literature reveals that in most cases the comparisons of redox potential values are far from accurate, and therefore, caution should be exercised when one is comparing the redox properties of complexes measured in CH 3 CN solutions versus different reference electrodes.
1,399 citations
Related Topics (5)
Performance Metrics
| Year | Papers |
|---|---|
| 2025 | 59 |
| 2024 | 98 |
| 2023 | 135 |
| 2022 | 217 |
| 2021 | 240 |
| 2020 | 282 |