Troilite

Abstract: We define a model of the compositon and abundances of grains and gases in molecular cloud cores and accretion disks around young stars by employing a wide range of astronomical data and theory, the composition of primitive bodies in the solar system, and solar elemental abundances. In the coldest portions of these objects, we propose that the major grain species include olivine (Fe, Mg, 2SiO4), orthopyroxene (Fe, Mg, SiO3), volatile and refractory organics, water ice, troilite (FeS), and metallic iron. This compositional model differs from almost all previous models of the interstellar medium (ISM) by having organics as the major condensed C species, rather than graphite; by including troilite as a major grain species; and by specifying the mineralogical composition of the condensed silicates. Using a combination of laboratory measurements of optical constants and asymptotic theory, we derive values of the real and imaginary indices of refraction of these grain species over a wavelength range that runs from the vacuum ultraviolet (UV) to the radio domain. The above information on grain properties is used to estimate the Rosseland mean opacity of the grains and their monochromatic opacity.

Abstract: Approximately 275 mineral species have been identified in meteorites, reflecting diverse redox environments, and, in some cases, unusual nebular formation conditions. Anhydrous ordinary, carbonaceous and R chondrites contain major olivine, pyroxene and plagioclase; major opaque phases include metallic Fe-Ni, troilite and chromite. Primitive achondrites are mineralogically similar. The highly reduced enstatite chondrites and achondrites contain major enstatite, plagioclase, free silica and kamacite as well as nitrides, a silicide and Ca-, Mg-, Mn-, Na-, Cr-, K- and Ti-rich sulfides. Aqueously altered carbonaceous chondrites contain major amounts of hydrous phyllosilicates, complex organic compounds, magnetite, various sulfates and sulfides, and carbonates. In addition to kamacite and taenite, iron meteorites contain carbides, elemental C, nitrides, phosphates, phosphides, chromite and sulfides. Silicate inclusions in IAB/IIICD and lIE iron meteorites consist of mafic silicates, plagioclase and various sulfides, oxides and phosphates. Eucrites, howardites and diogenites have basaltic to orthopyroxenitic compositions and consist of major pyroxene and calcic plagioclase and several accessory oxides. Ureilttes .are made up mainly of calcic, chromian olivine and low-Ca clinopyroxene embedded in a carbonaceous matrix; accessory phases include the C polymorphs graphite, diamond, lonsdaleite and chaoite as well as metallic Fe-Ni, troilite and halides. Angrites are achondrites rich in fassaitic pyroxene (i.e. , AI-Ti diopside); minor olivine with included magnesian kirschsteinite is also present. Martian meteorites comprise basalts, Iherzolites, a dunite and an orthopyroxenite. Major phases include various pyroxenes and olivine; minor to accessory phases include various sulfides, magnetite, chromite and Ca-phosphates. Lunar meteorites comprise mare basalts with major augite and calcic plagioclase and anorthositic breccias with major calcic plagioclase. Several meteoritic phases were formed by shock metamorphism. Martensite (a2-fe,Ni) has a distorted body-centered-cubic structure and formed by a shear transformation from taenite during shock reheating and rapid cooling. The C polymorphs diamond, lonsdaleite and chaoite formed by shock from graphite. Suessite formed in the North Haig ureilite by reduction of Fe and Si (possibly from olivine) via reaction with carbonaceous matrix material. Ringwoodite, the spinel form of (Mg,Fe)2Si04, and majorite, a polymorph of (Mg,Fe)Si03 with the garnet structure, formed inside shock veins in highly shocked ordinary chondrites. Secondary minerals in meteorite finds that formed during terrestrial weathering include oxides and hy-. droxides formed directly from metallic Fe-Ni by oxidation, phosphates formed by the alteration of schreibersite, and sulfates formed by alteration of troilite.

Abstract: The opaque and semiopaque minerals were examined in polished sections of 135 stony meteorites. The following minerals, all of which were previously known from meteorites, were observed: kamacite and taenite and intergrowths of these minerals (plessite), cohenite, schreibersite, graphite, native copper, native gold, troilite, pentlandite, oldhamite, daubreelite, chromite, magnetite, and ilmenite. The following minerals, which are well known from terrestrial occurrences, were observed for the first time in stony meteorites: chalcopyrrhotite, valleriite, sphalerite, chalcopyrite, pyrite, and bravoite. Entirely new minerals observed were (Ni, Fe) xSiy, (Mg, Fe, Ca, Mn)S with NaCl structure, and a hexagonal layer-structure mineral containing Fe-C-S, as well as the following minerals identified by letters: A, a strongly anisotropic, dark yellow-green mineral; B, a mineral occurring in thin lamellas as a decomposition product of A; C, a dark olive-colored mineral; D, a colorless transparent mineral with high refractive index, replacing ilmenite and chromite; E, a dark brown, probably isotropic mineral; F, a white mineral, probably containing arsenic; G, a light blue mineral; H, a yellow, almost metallic mineral; I, a colorless spinel-like mineral, with exsolution of ilmenite; K, a very dark gray sulfide; and L, a very strongly pleochroic mineral. Structures and textures as well as effects of weathering processes are described.