TL;DR: In this article, the pyrolysis characteristics of three main components (hemicellulose, cellulose and lignin) of biomass were investigated using, respectively, a thermogravimetric analyzer (TGA) with differential scanning calorimetry (DSC) detector and a pack bed.
TL;DR: An overview of the research on biomass upgrading by torrefaction for the production of biofuels is presented in this article, where the removal of oxygen from biomass aims to produce a fuel with increased energy density by decomposing the reactive hemicellulose fraction.
Abstract: An overview of the research on biomass upgrading by torrefaction for the production of biofuels is presented. Torrefaction is a thermal conversion method of biomass in the low temperature range of 200–300 °C. Biomass is pre-treated to produce a high quality solid biofuel that can be used for combustion and gasification. In this review the characteristics of torrefaction are described and a short history of torrefaction is given. Torrefaction is based on the removal of oxygen from biomass which aims to produce a fuel with increased energy density by decomposing the reactive hemicellulose fraction. Different reaction conditions (temperature, inert gas, reaction time) and biomass resources lead to various solid, liquid and gaseous products. A short overview of the different mass and energy balances is presented. Finally, the technology options and the most promising torrefaction applications and their economic potential are described.
TL;DR: In this article, a large number of experiments on biochar production is presented to give a general overview of the properties that can be achieved by feedstock selection and process design, including torrefaction as well as slow pyrolysis at high temperatures.
TL;DR: In this article, the authors provide a comprehensive review of research progress in this area, drawing on major contributions from two major research groups of the authors on torrefaction and densification at Canada and Taiwan as well as literatures.
Abstract: Torrefaction is a mild pyrolysis, which has been explored for the pretreatment of biomass to increase the heating value and hydrophobicity. Due to its potential applications for making torrefied pellets, which can be used as a high quality feedstock in gasification for high quality syngas production and as a substitute for coal in thermal power plants and metallurgical processes, torrefaction and densification have attracted great interest in recent years from both academia and bioenergy industry. This paper provides a comprehensive review of research progresses in this area, drawing on major contributions from two major research groups of the authors on torrefaction and densification at Canada and Taiwan as well as literatures. It is revealed that torrefaction of various biomass species and their major components, lignin, cellulose and hemicelluloses have been extensively studied in thermogravimetric apparatus (TGA) under both inert (N 2 ) and oxidative (O 2 , H 2 O) environments to elucidate the weight loss as a function of temperature, particle size and time. It was found that the higher heating value and saturated water uptake of torrefied biomass were a strong function of weight loss, which represents the degree of torrefaction. When torrefied sawdust is compressed into torrefied pellets, more mechanical energy is consumed and higher die temperature is required to make torrefied pellets of similar density and hardness as regular pellets. Simple economics analyses based on laboratory scale experimental data showed that because of the potential savings from pellets transport, handling and storage logistics, the overall cost for torrefied pellets can be lower than regular pellets in European market for both European and Canadian pellets. The gasification could be improved in terms of both energy efficiency and syngas quality because of the removal of oxygenated volatile compounds from torrefied biomass.
TL;DR: Basu et al. as mentioned in this paper provide a comprehensive overview of the design, analysis, and operational aspects of biomass gasification, pyrolysis, and torrefaction in a single easy-to-access source.
Abstract: Biomass is the most widely used non-fossil fuel in the world. Biomass resources show a considerable potential in the long term given the increasing proliferation of dedicated energy crops for biofuels. With a dedicated focus on the design, analysis, and operational aspects of biomass gasification, pyrolysis, and torrefaction, Dr. Basu's book offers holistic, comprehensive coverage of biomass in its gas, liquid, and solid states in a single easy-to-access source. This versatile resource not only explains the basic principles of energy conversion systems, but also provides valuable insight into the design of biomass gasifiers. The author provides many worked design problems, step-by-step design procedures and real data on commercially operating systems.
Contains new and updated step-by-step process flow diagrams, design data and conversion charts, and numerical examples with solutions
Includes chapters dedicated to evolving torrefaction technologies, practicing option of biomass cofiring, and biomass conversion economics
Expanded coverage of syngas and other Fischer-Tropsch alternatives
Spotlights advanced processes such as supercritical water gasification and torrefaction of biomass.
Provides available research results in an easy-to-use design methodology