TL;DR: In this article, the shape-from-shading problem is formulated as a nonlinear first-order partial differential equation in surface elevation and the problem of finding a surface orientation field that minimizes the integral of the brightness error is solved.
Abstract: We develop a systematic approach to the discovery of parallel iterative schemes for solving the shape-from-shading problem on a grid. A standard procedure for finding such schemes is outlined, and subsequently used to derive several new ones. The shape-from-shading problem is known to be mathematically equivalent to a nonlinear first-order partial differential equation in surface elevation. To avoid the problems inherent in methods used to solve such equations, we follow previous work in reformulating the problem as one of finding a surface orientation field that minimizes the integral of the brightness error. The calculus of variations is then employed to derive the appropriate Euler equations on which iterative schemes can be based. The problem of minimizing the integral of the brightness error term is ill posed, since it has an infinite number of solutions in terms of surface orientation fields. A previous method used a regularization technique to overcome this difficulty. An extra term was added to the integral to obtain an approximation to a solution that was as smooth as possible. We point out here that surface orientation has to obey an integrability constraint if it is to correspond to an underlying smooth surface. Regularization methods do not guarantee that the surface orientation recovered satisfies this constraint. Consequently, we attempt to develop a method that enforces integrability, but fail to find a convergent iterative scheme based on the resulting Euler equations. We show, however, that such a scheme can be derived if, instead of strictly enforcing the constraint, a penalty term derived from the constraint is adopted. This new scheme, while it can be expressed simply and elegantly using the surface gradient, unfortunately cannot deal with constraints imposed by occluding boundaries. These constraints are crucial if ambiguities in the solution of the shape-from-shading problem are to be avoided. Differrent schemes result if one uses different parameters to describe surface orientation. We derive two new schemes, using unit surface normals, that facilitate the incorporation of the occluding boundary information. These schemes, while more complex, have several advantages over previous ones.
TL;DR: In this paper, a novel scheme has been developed for data reconstruction within a Godunov-type method for solving the shallow-water equations with source terms, which is suitable for both steady and unsteady flow problems.
TL;DR: A gradient phosphorus-doped CdS (CdS-P) homojunction nanostructure is reported, creating an oriented built-in electric-field for efficient extraction of carriers from inside to surface of the photocatalyst, providing a new approach to design other types of semiconductor photocatalysts for efficient solar-to-chemical conversion.
Abstract: Element doping has been extensively attempted to develop visible-light-driven photocatalysts, which introduces impurity levels and enhances light absorption However, the dopants can also become recombination centers for photogenerated electrons and holes To address the recombination challenge, we report a gradient phosphorus-doped CdS (CdS-P) homojunction nanostructure, creating an oriented built-in electric-field for efficient extraction of carriers from inside to surface of the photocatalyst The apparent quantum efficiency (AQY) based on the cocatalyst-free photocatalyst is up to 82% at 420 nm while the H2 evolution rate boosts to 1943 μmol·h–1·mg–1, which is 583 times higher than that of pristine CdS This concept of oriented built-in electric field introduced by surface gradient diffusion doping should provide a new approach to design other types of semiconductor photocatalysts for efficient solar-to-chemical conversion
TL;DR: The preparation and characterization of gradient polymer surfaces are described, presenting an organized and detailed overview of the state-of-the-art, and the interactions of these surfaces with biological species important in the understanding of the basic science for biomedical application are concentrated.
TL;DR: In this article, the performance of commercial scanning white light interferometers in a range of measurement tasks was examined, and it was found that most instruments report errors when used in regions close to a discontinuity or those with a surface gradient that is large compared to the acceptance angle of the objective lens.
Abstract: This paper examines the performance of commercial scanning white light interferometers in a range of measurement tasks. A step height artefact is used to investigate the response of the instruments at a discontinuity, while gratings with sinusoidal and rectangular profiles are used to investigate the effects of surface gradient and spatial frequency. Results are compared with measurements made with tapping mode atomic force microscopy and discrepancies are discussed with reference to error mechanisms put forward in the published literature. As expected, it is found that most instruments report errors when used in regions close to a discontinuity or those with a surface gradient that is large compared to the acceptance angle of the objective lens. Amongst other findings, however, we report systematic errors that are observed when the surface gradient is considerably smaller. Although these errors are typically less than the mean wavelength, they are significant compared to the vertical resolution of the instrument and indicate that current scanning white light interferometers should be used with some caution if sub-wavelength accuracy is required.