Topic
Stannole
About: Stannole is a research topic. Over the lifetime, 62 publications have been published within this topic receiving 1215 citations.
Papers published on a yearly basis
Papers
TL;DR: A series of group 14 metalloles, from silole to stannole, together with cyclopentadiene, having two thienyl groups at the 2,5 positions, have been prepared.
141 citations
TL;DR: In this article, the first isolable electronically unsymmetrical silylene, dineopentylpyrido[b]-1,3,2λ2-diazasilol, and the analogous germylene and stannylene (right) are presented and characterized by NMR and photoelectron spectroscopy.
Abstract: The first isolable electronically unsymmetrical silylene, dineopentylpyrido[b]-1,3,2λ2-diazasilol, and the analogous germylene and stannylene (right) are presented and characterized by NMR and photoelectron spectroscopy. In contrast to nonisolable analogous pyrido[c] derivatives, the pyrido[b] derivatives possess a symmetrical π charge density distribution in the HOMO from a nodal plane through the pyrido nitrogen atom.
113 citations
TL;DR: The synthesis, structures, and physical and chemical properties of mono-and dianions of group 14 metalloles (1-metallacyclopentadiene), heavier congeners of the cyclopentadienyl anion, are described in this article.
101 citations
TL;DR: The first tin-analog of the cyclopentadienyl anion, dilithiostannoles, were successfully synthesized by reduction of the corresponding 1,1-diphenyl derivatives.
60 citations
TL;DR: In this paper, the synthesis of silyl-substituted dilithiostannoles, which were characterized by NMR spectroscopy and X-ray diffraction analysis, was reported.
53 citations
Related Topics (5)
Performance Metrics
| Year | Papers |
|---|---|
| 2021 | 2 |
| 2020 | 2 |
| 2019 | 5 |
| 2018 | 3 |
| 2017 | 1 |
| 2016 | 2 |