Topic
Osmocene
About: Osmocene is a research topic. Over the lifetime, 94 publications have been published within this topic receiving 2294 citations. The topic is also known as: di(cyclopentadienyl)osmium.
Papers published on a yearly basis
Papers
TL;DR: In this article, the LC separation of 13 enantiomeric pairs of ferrocene, ruthenocene, and osmocene analogues is described, and the effect of solute structure and size on resolution and separation efficiency is examined.
Abstract: The LC separation of 13 enantiomeric pairs of ferrocene, ruthenocene, and osmocene analogues is described. Recently developed ..beta..-cyclodextrin bonded columns, which contain no interfering nitrogen or sulfur linkages, are particularly well suited to the separation of these compounds. The effect of solute structure and size on resolution and separation efficiency is examined. Both the application of this system and the mechanism of separation are discussed. 33 references, 3 figures, 1 table.
178 citations
TL;DR: In this article, the transition state for electrophilic substitution of ferrocene, ruthenocene and osmocene may involve initial interaction of the electrophile with the metal atom.
Abstract: Ferrocene recently has been shown to form a stable complex salt of composition (C_(10_H_(10)Fe•HAlCl_4) in the presence of aluminum chloride and hydrogen chloride. This finding, together with the suggestion that the transition state for electrophilic substitution of ferrocene, ruthenocene and osmocene may involve initial interaction of the electrophile with the metal atom, prompted us to examine then.m.r. spectra of these moetallcenes in media of high acidity.
137 citations
TL;DR: In this article, the half-wave potentials (E 1 2 ) and different σ sets have been investigated at dropping mercury (DME) and Pt-rotating disc (Pt- electrode) electrodes.
88 citations
TL;DR: In this article, the products of chemical and electrochemical oxidation of metallocenes, (C 5 H 5 ) 2 M (M Fe, Ru, Os), were investigated.
65 citations
Related Topics (5)
Performance Metrics
| Year | Papers |
|---|---|
| 2021 | 1 |
| 2019 | 3 |
| 2016 | 5 |
| 2015 | 2 |
| 2014 | 4 |
| 2013 | 2 |