TL;DR: In this article, a procedure is presented which employs sodium dithionite (Na2S2O4, hyposulfite, or "hydrosulfite") as the reductor, and 0.3 molar citrate with or without Fe-3 specific Versene as the chelating reagent.
Abstract: Iron oxide coatings or crystals must be removed from soils in which they are found in many mineralogical techniques for identification of colloidal layer silicates as well as the identification of silt and sand grains with the polarizing microscope. A procedure is presented which employs sodium dithionite (Na2S2O4, hyposulfite, or "hydrosulfite") as the reductor, and 0.3 molar citrate with or without Fe-3 specific Versene as the chelating reagent. It is a neutral system the pH of which is kept at 7.3. The reaction is fast, as much as 20% of iron oxides (hematite, geothite, or limonite but not magnetite or ilmenite) being removed from a soil in 15 minutes, and does not precipitate either elemental sulfur or iron sulfides. Like other procedures, it causes some decrease of exchange capacity of layer silicates which contain iron, and at the same time may increase the exchange capacity of kaolinic soils. View complete article To view this complete article, insert Disc 2 then click button8
TL;DR: In this article, massive sulfide deposits were discovered from the diving saucer Cyana on the accreting plate boundary region of the East Pacific Rise near 21°N, where they formed conical and tubular structures lying on a basaltic basement.
Abstract: Massive sulfide deposits were discovered from the diving saucer Cyana on the accreting plate boundary region of the East Pacific Rise near 21°N. The deposits form conical and tubular structures lying on a basaltic basement. Mineralogical and geochemical analyses showed two main types of intimately associated products: a polymetallic sulfide-rich material composed of pyrite and marcasite in association, zinc-rich phases, and copper-rich compounds, and an iron-rich oxide and hydroxide material (also called gossan) composed largely of goethite and limonite. Silicate phases such as opaline, silica, iron-silicon clay, and trace amounts of mica and zeolite are encountered in both types of material. Possible mechanisms for the formation of the sulfide deposits on the East Pacific Rise are discussed.
TL;DR: In this article, it was observed that limonite consists of aggregates of needle-like particles of goethite compacted together, and the grain model was finally proposed to best describe nickel dissolution kinetics.
TL;DR: Three permanent magnet arrays were mounted on each Viking lander: a strong array fixed on a photometric reference test chart on top of the landers; and two arrays, one strong and one weak, incorporated into the backhoe of the surface sampler as discussed by the authors.
Abstract: Three permanent magnet arrays were mounted on each Viking lander: a strong array fixed on a photometric reference test chart on top of the landers; and two arrays, one strong and one weak, incorporated into the backhoe of the surface sampler. Some or all of the magnetic particles detected could be highly magnetic unoxidized mineral grains (metallic Fe, magnetite, pyrrhotite) forming the core beneath a reddish coating of limonite or hematite; or grains composed of gamma-Fe2O3, with and without other iron oxides; or igneous rock (or mineral particles) which consist of an admixture of unweathered silicate material or minerals with a significant fraction of highly magnetic phase, again with a reddish coating; they could be also igneous rock or mineral particles, intrinsically nonmagnetic, but having a reddish coating containing gamma-Fe2O3; or clay mineral particles which contain and/or are coated with Fe2O3, of which a substantial fraction is in the gamma-Fe2O3 form.
TL;DR: The changes that take place in the clay minerals, illite and montmorillonite, when they are heated at various temperatures up to 1400°C are discussed in this article.
Abstract: Samples of three purified illites, one purified montmorillonite, and one natural clay containing montmorillonite, quartz, and limonite were heated at successive temperatures up to 1400°C. X-ray and optical determinations were made on all samples. The changes that take place in the clay minerals, illite and montmorillonite, when they are heated at various temperatures up to 1400°C. are discussed.