TL;DR: This work explored a systematic approach to optimize a matrix of calibration standards using a D-optimal experimental design and found the Design of Experiments-based regression model to be the more practical method for building calibration models, with fewer samples, to obtain informative analytical data from Raman spectra.
Abstract: Chemical processing of highly radioactive materials commonly takes place in heavily shielded hot cells. The remote, real-time monitoring of chemical processing streams via optical spectroscopic tec...
TL;DR: In this article, a method and apparatus are disclosed for carrying out repair, maintenance or testing of apparatus, components and the like in hot cells, more particularly hot cells of reprocessing plants for spent nuclear fuels.
Abstract: A method and apparatus are disclosed for carrying out repair, maintenance or testing of apparatus, components and the like in hot cells, more particularly hot cells of reprocessing plants for spent nuclear fuels. The position of damage zones is detected and ascertained with the use of coordinates. Replacement parts and tools are moved into the maintenance and work position in dependence upon the coordinate data, and the repair or maintenance work is automatically carried out under computer control, with remote operation and remote monitoring. For carrying out the work, computer-controlled handling machines and manipulators are used which are adapted to travel in controllable manner in the hot cell. The monitoring and detecting, using coordinates, of damage zones and defects may be carried out with the use of cameras and/or leak detectors.
TL;DR: In this paper, a method and apparatus for carrying out repair, maintenance or testing of apparatus, components and the like in hot cells, more particularly hot cells of reprocessing plants for spent nuclear fuels is disclosed.
Abstract: A method and apparatus are disclosed for carrying out repair, maintenance or testing of apparatus, components and the like in hot cells, more particularly hot cells of reprocessing plants for spent nuclear fuels The position of damage zones is detected and ascertained with the use of coordinates Replacement parts and tools are moved into the maintenance and work position in dependence upon the coordinate data, and the repair or maintenance work is automatically carried out under computer control, with remote operation and remote monitoring For carrying out the work, computer-controlled handling machines and manipulators are used which are adapted to travel in controllable manner in the hot cell The monitoring and detecting, using coordinates, of damage zones and defects may be carried out with the use of cameras and/or leak detectors
TL;DR: In this article, the primary chamber of a melter is used for vitrification and the secondary chambers are used to add hazardous and/or radioactive containing materials, and the glass is homogenized with the plutonium feed.
Abstract: In this invention radioactive or hazardous containing materials are vitrified in a melter having two or more chambers. Glass feed materials are added to the primary chamber of the melter and they are heated to a molten glass which is then transported to one or more secondary chambers where hazardous and/or radioactive containing materials are added and are encapsulated and/or melted. In addition, the non-plutonium part of a glass feed can be melted in a non-radioactive environment which permits contact operations and maintenance; no radioactive shielding; and a conventional off gas system-similar to commercial vitrification plants. The hot molten "clean" glass is directed into a radioactive containment such as a "glove box"; shielded "glove box"; or hot cell, or a combination of these. By delivering hot "clean" glass from a melter including non-radioactive materials, 90% of the off gases will be non-radioactive. Thereby only minimum heating is needed in the radioactive containment resulting in very significant reductions in size of the maintenance requirements for the radioactive portion of the process. In the radioactive portion, the glove box will include means for adding plutonium feed. The glass melt will be homogenized with the plutonium feed, optionally by additional stirring. Once the plutonium glass is sufficiently homogeneous, it can be cooled in the container in the glove box or the container becomes a disposal container for the glass. If the melt chamber is different than the container, the melt is discharged to a separate container, all within the glove box, for subsequent disposal.