Topic
Grandisol
About: Grandisol is a research topic. Over the lifetime, 131 publications have been published within this topic receiving 1990 citations. The topic is also known as: 2-[(1R,2S)-1-methyl-2-prop-1-en-2-ylcyclobutyl]ethanol.
Papers published on a yearly basis
Papers
TL;DR: Aus Methacrolein (I) entsteht mit Thiophenol (II) das Addukt (III), das mit l-Lithiocyclopropylphenylsulfid and nachfolgender Umlagerung in das Cyclobutanon (IV) ubergeht as discussed by the authors.
Abstract: Aus Methacrolein (I) entsteht mit Thiophenol (II) das Addukt (III), das mit l-Lithiocyclopropylphenylsulfid und nachfolgender Umlagerung in das Cyclobutanon (IV) ubergeht.
97 citations
TL;DR: The intermolecular [2+2] photocycloaddition of typical cyclic α,β-unsaturated enones, such as 2-cyclohexenone, with olefins was performed in moderate to good yields and with high enantioselectivity.
Abstract: The intermolecular [2+2] photocycloaddition of typical cyclic α,β-unsaturated enones, such as 2-cyclohexenone, with olefins was performed in moderate to good yields (42–82%) and with high enantioselectivity (82%–96% ee). An unusual substitution pattern at the chiral oxazaborolidine-AlBr3 Lewis acid complex that promotes the reaction was found to be crucial for the success of the reaction. The method was applied to the enantioselective synthesis of the monoterpene (−)-grandisol, which could be accomplished in six steps and with an overall yield of 13% starting from 3-methyl-2-cyclohexenone.
96 citations
Related Topics (5)
Performance Metrics
| Year | Papers |
|---|---|
| 2021 | 1 |
| 2019 | 2 |
| 2018 | 3 |
| 2013 | 1 |
| 2012 | 4 |
| 2011 | 3 |