TL;DR: The fracture toughness, fracture energy, and fatigue properties of an epoxy polymer reinforced with various weight fractions of functionalized graphene sheets, and under fatigue conditions, are reported.
Abstract: Graphene, a single-atom-thick sheet of sp-bonded carbon atoms, has generatedmuch interest due to its high specific area and novel mechanical, electrical, and thermal properties. Recent advances in the production of bulk quantities of exfoliated graphene sheets from graphite have enabled the fabrication of graphene–polymer composites. Such composites show tremendous potential for mechanical-property enhancement due to their combination of high specific surface area, strong nanofiller–matrix adhesion and the outstanding mechanical properties of the sp carbon bonding network in graphene. Graphene fillers have been successfully dispersed in poly(styrene), poly(acrylonitrile) and poly(methyl methacrylate) matrices and the responses of their Young’s modulus, ultimate tensile strength, andglass-transition temperaturehave been characterized. However, to the best of our knowledge there is no report on the fracture toughness and fatigue properties of graphene–polymer composites. Fracture toughness describes the ability of a material containing a crack to resist fracture and it is a critically important material property for design applications. Fatigue involves dynamic propagation of cracks under cyclic loading and it is one of the primary causes of catastrophic failure in structural materials. Consequently, the material’s resistance to fracture and fatigue crack propagation are of paramount importance to prevent failure. Herein we report the fracture toughness, fracture energy, and fatigue properties of an epoxy polymer reinforced with various weight fractions of functionalized graphene sheets. Remarkably, only 0.125% weight of functionalized graphene sheets was observed to increase the fracture toughness of the pristine (unfilled) epoxy by 65% and the fracture energy by 115%.Toachievecomparableenhancement,carbonnanotube (CNT) and nanoparticle epoxy composites require one to two orders of magnitude larger weight fraction of nanofillers. Under fatigue conditions, incorporation of 0.125% weight of functionalized graphene sheets drastically reduced the rate of crack propagation in the epoxy 25-fold. Fractography analysis
TL;DR: In this paper, the effects of fabrication orientation, surface polishing, and hot isostatic pressing upon mechanical behavior of four metallic alloys fabricated with layered, laser-heated methods of additive manufacturing (AM) was compared to that of similar alloys produced with conventional methods (wrought and machined).
Abstract: Mechanical behavior of four metallic alloys fabricated with layered, laser-heated methods of additive manufacturing (AM) was compared to that of similar alloys produced with conventional methods (wrought and machined). AM materials were produced by a leading commercial service provider, as opposed to incorporating material specimens produced by unique or specially-adapted equipment. The elastic moduli were measured in flexure, stress–strain characteristics were measured in tensile deformation, and fatigue strengths were measured in fully reversed bending. The effects of fabrication orientation, surface polishing, and hot isostatic pressing upon mechanical behavior were studied. The fatigue strengths exhibited by SLM AlSi10Mg and DMLS Ti6Al4V in the as-fabricated condition proved to be significantly inferior to that of conventional material. These lower fatigue strengths are a consequence of multiple fatigue cracks initiating at surface defects, internal voids and microcracks, and growing simultaneously during cyclic loading. Measured fatigue strengths of DMLS 316L and 17-4PH approached those of corresponding wrought materials when subjected to principal stresses aligned with the build planes. When cyclic stresses were applied across the build planes of the DMLS stainless steels, fatigue fractures often developed prematurely by separation of material. Post-processing the DMLS Ti6Al4V and SS316L with hot isostatic pressure elevated the fatigue strength significantly. Measurements of surface roughness with an optical profilometer, examinations of the material microstructures, and fractography contribute to an understanding of the mechanical behavior of the additive materials.
TL;DR: In this paper, the effect of the microstructure on the tensile properties of additive manufacturing (AM) of Ti alloys has been investigated. And the authors found that the mechanical anisotropy of the parts was discussed in relation to the crystallographic texture, phase composition and the predominant fracture mechanisms.
Abstract: Recent research on the additive manufacturing (AM) of Ti alloys has shown that the mechanical properties of the parts are affected by the characteristic microstructure that originates from the AM process. To understand the effect of the microstructure on the tensile properties, selective laser melted (SLM) Ti–6Al–4V samples built in three different orientations were tensile tested. The investigated samples were near fully dense, in two distinct conditions, as-built and stress relieved. It was found that the build orientation affects the tensile properties, and in particular the ductility of the samples. The mechanical anisotropy of the parts was discussed in relation to the crystallographic texture, phase composition and the predominant fracture mechanisms. Fractography and electron backscatter diffraction (EBSD) results indicate that the predominant fracture mechanism is intergranular fracture present along the grain boundaries and thus provide and explain the typical fracture surface features observed in fracture AM Ti–6Al–4V.
TL;DR: In this paper, a comprehensive study was carried out on series of nanocomposites containing varying amounts of nanoparticles, either titanium dioxide (TiO 2 ) or aluminium oxide (Al 2 O 3 ).
TL;DR: In this paper, the relative importance of these mechanisms for different fracture modes and materials are discussed based on detailed fractographic observations and critical experiments, and the evidence supporting various hypotheses, such as those based on hydride formation, hydrogenenhanced decohesion, hydrogen-enhanced localised plasticity, adsorption-induced dislocation emission, and hydrogen-vacancy interactions, are summarised.
Abstract: Abstract Mechanisms of hydrogen embrittlement in steels and other materials are described, and the evidence supporting various hypotheses, such as those based on hydride formation, hydrogen-enhanced decohesion, hydrogen-enhanced localised plasticity, adsorption-induced dislocation emission, and hydrogen-vacancy interactions, are summarised. The relative importance of these mechanisms for different fracture modes and materials are discussed based on detailed fractographic observations and critical experiments.