Topic
Fluoroamine
About: Fluoroamine is a research topic. Over the lifetime, 54 publications have been published within this topic receiving 985 citations. The topic is also known as: monofluoroamine & monofluoroammonia.
Papers published on a yearly basis
Papers
TL;DR: A novel palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes has been developed, in which AgF was used as a key fluorinating reagent and PhI(OPiv)(2) as oxidant.
Abstract: A novel palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes has been developed, in which AgF was used as a key fluorinating reagent and PhI(OPiv)2 as oxidant. The reaction afforded vicinal fluoroamine products with very high regioselectivity. A Pd(II/IV) catalytic cycle was proposed, and preliminary mechanistic studies indicated that direct reductive elimination of Pd(IV) intermediates is favored, albeit competing with SN2 nucleophilic attack by fluorine, to form a C−F bond.
294 citations
TL;DR: A novel palladium-catalyzed intermolecular aminofluorination of styrenes, with N-fluorobenzenesulfonimide (NFSI) functioning not only as a fluorinating re agent but also as an aminating reagent, has been developed, which afforded vicinal fluoroamine products with very high regioselectivity.
Abstract: A novel palladium-catalyzed intermolecular aminofluorination of styrenes, with N-fluorobenzenesulfonimide (NFSI) functioning not only as a fluorinating reagent but also as an aminating reagent, has been developed. The reaction afforded vicinal fluoroamine products with very high regioselectivity. This transformation may involve fluoropalladation of styrene as a key step for C-F bond formation. The bidental nitrogen ligand is crucial to achieving the transformation successfully.
269 citations
TL;DR: A combination of two Lewis acids, (salen)Co and an achiral Ti(IV) cocatalyst, provided optimal reactivity and enantioselectivity for the trans β-fluoroamine product and the use of a chelating aziridine protecting group was crucial.
97 citations
TL;DR: In this article, a new fluoroamine compound was synthesized by aminating the perfluoroacrylate compound and the synthesized fluroamine was used to modify the surface of polyacrylonitrile (PAN) nanofibers and the fog harvesting ability of the modified nanofiber was investigated.
56 citations
TL;DR: The results suggest that the investigated ligands might have microscopic nonlinear optical (NLO) behavior with nonzero values, implying nonzero microscopic first hyperpolarizability.
51 citations
Related Topics (5)
Performance Metrics
| Year | Papers |
|---|---|
| 2018 | 3 |
| 2017 | 2 |
| 2016 | 1 |
| 2014 | 1 |
| 2013 | 1 |
| 2012 | 3 |