About: Fergusonite is a research topic. Over the lifetime, 204 publications have been published within this topic receiving 4152 citations. The topic is also known as: fergusonite & fergusonite group.
TL;DR: In this article, a systematic study with laser ablation, scanning electron microscopy and electron microprobe revealed that ∼70-95 wt% of REE, Y, Th and U in granite rocks and crustal protoliths reside within REEYThU-rich accessories whose nature, composition and associations change with the rock aluminosity.
Abstract: A systematic study with laser ablation—ICP-MS, scanning electron microscopy and electron microprobe revealed that ∼70–95 wt% of REE (except Eu), Y, Th and U in granite rocks and crustal protoliths reside within REEYThU-rich accessories whose nature, composition and associations change with the rock aluminosity. The accessory assemblage of peraluminous granites, migmatites and high-grade rocks is composed of monazite, xenotime (in low-Ca varieties), apatite, zircon, Thorthosilicate, uraninite and betafite-pyrochlore. Metaluminous granites have allanite, sphene, apatite, zircon, monazite and Thorthosilicaie. Peralkaline granites have aeschinite, fergusonite, samarskite, bastnaesite, fluocerite, allanite, sphene, zircon, monazite, xenotime and Th-orthosilicate. Granulite-grade garnets are enriched in Nd and Sm by no less than one order of magnitude with respect to amphibolite-grade garnets. Granulitegrade feldspars are also enriched in LREE with respect to amphibolite-grade feldspars. Accessories cause non-Henrian behaviour of REE, Y, Th and U during melt—solid partitioning. Because elevated fractions of monazite, xenotime and zircon in common migmatites are included within major minerals, their behaviour during anatexis is controlled by that of their host. Settling curves calculated for a convecting magma show that accessories are too small to settle appreciably, being separated from the melt as inclusions within larger minerals. Biotite has the greatest tendency to include accessories, thereby indirectly controlling the geochemistry of REE, Y, Th and U. We conclude that REE, Y, Th and U are unsuitable for petrogenetical modelling of granitoids through equilibrium-based trace-element fractionation equations.
TL;DR: In this article, the luminescence of compounds LnTaOO4 (Ln = La, Gd, Y and Lu) is reported, which is ascribed to energy transfer from TaO4 to Gd followed by concentration quenching.
TL;DR: The Baerzhe Zirconium, rare earth elements (REE), and Nb are primarily hosted by zircon, yttroceberysite, fergusonite, ferrocolumbite, and pyrochlore as discussed by the authors.
Abstract: The Baerzhe alkaline granite pluton hosts one of the largest rare metal (Zr, rare earth elements, and Nb) deposits in Asia. It contains a geological resource of about 100 Mt at 1.84 % ZrO2, 0.30 % Ce2O3, and 0.26 % Nb2O5. Zirconium, rare earth elements (REE), and Nb are primarily hosted by zircon, yttroceberysite, fergusonite, ferrocolumbite, and pyrochlore. Three types of zircon can be identified in the deposit: magmatic, metamict, and hydrothermal. Primary magmatic zircon grains occur in the barren hypersolvus granite and are commonly prismatic, with oscillatory zones and abundant melt and mineral inclusions. The occurrence of aegirine and fluorite in the recrystallized melt inclusions hosted in the magmatic zircon indicates that the parental magma of the Baerzhe pluton is alkali- and F-rich. Metamict zircon grains occur in the mineralized subsolvus granite and are commonly prismatic and murky with cracks, pores, and mineral inclusions. They commonly show dissolution textures, indicating a magmatic origin with later metamictization due to deuteric hydrothermal alteration. Hydrothermal zircon grains occur in mineralized subsolvus granite and are dipyramidal with quartz inclusions, with murky CL images. They have 608 to 2,502 ppm light REE and 787 to 2,521 ppm Nb, much higher than magmatic zircon. The texture and composition of the three types of zircon indicate that they experienced remobilization and recrystallization during the transition from a magmatic to a hydrothermal system. Large amounts of Zr, REE, and Nb were enriched and precipitated during the transitional period to form the giant low-grade Baerzhe Zr–REE–Nb deposit.
TL;DR: In this article, pressure dependence of all the Raman modes of the tetragonal scheelite phase PbWO4-I or stolzite, which is stable at ambient conditions, was reported.
Abstract: Room-temperature Raman scattering has been measured in lead tungstate up to 17 GPa. We report the pressure dependence of all the Raman modes of the tetragonal scheelite phase PbWO4-I or stolzite, space group I41 /a, which is stable at ambient conditions. Upon compression the Raman spectrum undergoes significant changes around 6.2 GPa due to the onset of a partial structural phase transition to the monoclinic PbWO4-III phase space group P21 /n. Further changes in the spectrum occur at 7.9 GPa, related to a scheelite-to-fergusonite transition. This transition is observed due to the sluggishness and kinetic hindrance of the I → III transition. Consequently, we found the coexistence of the scheelite, PbWO4-III, and fergusonite phases from 7.9 to 9 GPa, and of the last two phases up to 14.6 GPa. We have performed ab initio latticedynamics calculations, which have greatly helped us in assigning the Raman modes of the three phases and discussing their pressure dependence. The Raman modes of the free WO4 molecule are discussed.
TL;DR: A review of the application of the sulfuric acid bake process to ores/concentrates containing mainly monazite, xenotime and bastnasite, and other less common rare earth minerals including euxenite, samarskite, fergusonite, loparite, allanite, eudialyte and pyrochlore is given in this paper.