TL;DR: A sequential extraction procedure for fractionation of lead showed that lead did not exist as an exchangeable ion in geopolymers, regardless of activator type used, and aluminate activation is shown to be superior in the immobilisation of lead.
TL;DR: In this article, a two-stage high-low temperature vacuum distillation process was used to extract Pb from crude lead, waste Pb-Sn alloy and lead anode slime (LAS).
TL;DR: In this article, a randomized block experiment design was performed to investigate the capability of radish to extract lead from soils contaminated with lead resulting from air pollution, and the results indicated a non-linear positive relation between the lead concentrations in soil and that accumulated in plant roots and shoots.
Abstract: The objective of this study was to investigate the capability of radish to extract lead from soils contaminated with lead resulting from air pollution. A randomized block experiment design was performed. The soil was contamina ted with PbNO 3 and the treatments consisted of 180 (standard), 250, 350, 450, 800 and 1000 mg/kg lead. After development, plants were harvested and divided into shoots and roots. The lead content of each plant part as well as the soil-lead were measured. The results indicated a non-linear positive relation between the lead concentrations in soil and that accumulated in plant roots and shoots. By increasing the lead concentration in soil, its accumulation in plant tissues was also increased. Most of the extracted lead was accumulated in the roots (208.1 mg/kg) compared to shoots (27.25 mg/kg). Since radish can be seeded up to five times a year, and its yield may reach up to 20 t/ha, it can be used to remediate lead-polluted topsoils (0–10 cm).
TL;DR: Aims: Pacemaker and implantable‐cardioverter defibrillator lead infections widely increased with consequent need to accurately recognize responsible bacteria, and hence the need for accurate recognition of responsible bacteria.
Abstract: Aims: Pacemaker and implantable-cardioverter defibrillator lead infections widely increased with consequent need to accurately recognize responsible bacteria.
Methods: Between May 2003 and December 2007, we extracted 118 leads, 104 (87.3%) due to infections (sepsis, lead-associated endocarditis, pocket infection) or chronic draining sinus (with negative local bacteriological analyses). Swabs and tissue specimens from pocket and fragments of pin and tip of each extracted lead were obtained during extraction and sent for bacteriological examination.
Results: Cultures from explanted lead pins returned positive results in 100% of the cases presenting with local infections and in 92.5% of those with chronic draining sinus. In cases of sepsis, positive results of blood samples are less common than lead samples (58.3 vs 86.7, P = 0.02), the latter being more sensitive for infection diagnosis. Concordance between bacterial isolates from pocket and lead is quite low, approaching 45%, seemingly due to contamination effect. Concordance between isolates within the lead (pin and tip) is quite high, close to 70%, reflecting a more accurate expression of the real infection. In cases of sepsis, concordance between lead and blood samples, and mainly from tip and blood, is very high, resembling 80–85%; consequently bacterial isolates from the lead, particularly from lead tip, are clearly associated with clinical infections.
Conclusions: Our results strongly support the hypothesis that chronic draining sinus is often sustained by infection. Moreover, diagnostic accuracy of lead samples is higher not only than swabs and tissue samples, but also than blood samples to confirm an infection and to guide effective therapy.