TL;DR: In this article, the hydrometallurgical processes have been described for the recovery of zinc from the secondaries using sulphuric acid, hydrochloric acid and ammoniacal solution as lixiviants.
Abstract: Zinc containing wastes/secondaries viz. zinc ash, dross, flue dusts, sludge, residue etc. are generated in various chemical and metallurgical industries. The materials contain different level of impurities depending on the source. The hydrometallurgical processing is effective and flexible for treating such materials as it can control the different level of impurities. Depending on the nature and composition of the secondaries, a suitable lixiviant could be selected to dissolve the desired metals leaving gangue in the residue. In the present paper, the hydrometallurgical processes have been described for the recovery of zinc from the secondaries using sulphuric acid, hydrochloric acid, ammoniacal solution and sodium hydroxide etc. as lixiviants. The leach solution thus obtained has been purified with respect to dissolved impurities using precipitation, ion exchange or solvent extraction method. The metal or salt is produced from the purified solution by electrolysis or crystallization.
TL;DR: In this paper, the effect of different types of defects on the tensile behavior of an Al 7Si 0.4Mg casting alloy was studied and the experimental results were in agreement with the predictions of a simple analysis based on models for the growth of a plastic instability in a tensile sample.
Abstract: Samples containing either entrapped dross and oxide films, gas porosity or small drilled holes have been used to study the effect of different types of defects on the tensile behaviour of an Al 7Si 0.4Mg casting alloy. The tensile properties show little or no correlation with the bulk porosity content, especially in the case of samples containing dross and oxide films. In contrast, the decrease in tensile ductility and strength correlates with the area fraction of defects in the fracture surface of the samples. The experimental results are in agreement with the predictions of a simple analysis based on models for the growth of a plastic instability in a tensile sample.
TL;DR: Different types of aluminum dross, their environmental and health hazards, composition, and production process are described and direct and indirect recycling approaches and recovery strategies are focused on.
TL;DR: A review of the aluminium salt slag chemical and mineralogical characteristics, as well as various processes for metal recovery, recycling of sodium and potassium chlorides content back to the smelting process and preparation of value added products from the final non metallic residue are presented.
TL;DR: In this paper, the authors highlight the production capacity, type and quantity of solid wastes generated, their chemical composition and treatment/disposal options for the Indian aluminium, copper lead and zinc industries.
Abstract: This paper highlights the production capacity, type and quantity of solid wastes generated, their chemical composition and treatment/disposal options for the Indian aluminium, copper lead and zinc industries. Red mud, spent pot lining (SPL), fly ash from aluminium industries; scrap, slag, dross, reverts, slime, flue dust, mill scales, sludge etc. from copper industries; zinc tailing, slag, leach residue, jarosite residue, β-cake, etc. from zinc industries and BF slag, flue dust, ISF slag etc. from lead industries are the major solid waste generated from the process. Common practices of waste management in these industries are through recycling and recovering the metal values and dumping. Owing to the presence of the toxic elements in some of the solid wastes cause environmental degradation. Stringent pollution control rules are being enacted and implemented as a result of which all the metal producing industries in organised sector are now taking care of the environment and waste management related problems, but pollution from unorganized lead units are the major cause of concern. Permissible limits of toxic constituents in zinc based secondaries and threshold zinc concentration for both indigenous and imported raw material were worked out at National Metallurgical Laboratory (NML) and based on these results a recommendation to MOEF, Government of India was made to specify the permissible limits for the import of zinc secondaries. An overview of the attempts made to recycle/recover metal values and production of value added products, at NML are also mentioned in the text.