Dovyalis

Abstract: Phytochemical investigations of Dovyalis abyssinica, D. hebecarpa, and D. macrocalyx revealed two new spermidine-type alkaloids, dovyalicin E (3) and dovyalicin F (4), along with the previously described dovyalicin A (1), dovyalicin B (2), and dovyalicin C (5). In addition, a new phenol glucoside, 4-hydroxytremulacin (7), and the new 1,2-cyclohexanediol glucoside 9, as well as the known compounds methyl 1-hydroxy-6-oxocyclohex-2-enecarboxylate (6) and tremulacin (8), were isolated. The structures were established using homo- and heteronuclear two-dimensional NMR experiments and chiroptical methods. At ambient temperature, the N-disubstituted amide 4 exists as a mixture of cis and trans conformers. Variable-temperature 1H NMR studies showed that time-averaged spectra are obtainable at 348 K, and the activation parameters determined for the rotation about the amide bond were ΔH⧧ = 89 ± 4.6 kJ/mol, ΔS⧧ = 65 ± 14 kJ/mol·K, and ΔG⧧(298K) = 70 ± 4.5 kJ/mol.

Abstract: Dovyalis species Dovyalis abyssinica Warb. and Dovyalis hebecarpa Warb. were introduced into Brazil, but the fruit quality of these species is not appropriate for fresh consumption due to their high titratable acidity (TA) and low soluble solids content (SSC). With the selection of new D. abyssinica clones with lower acidity and the hybridization of these two dovyalis species (D. abyssinica and D. hebecarpa) the fruit quality improved and the better physical-chemical characteristics make them more suitable for fresh consumption. The objective of this study was to develop partial least squares (PLS) models using near infrared spectroscopy (NIRS) for the determination of SSC, TA and pH in intact dovyalis hybrid fruit (D. abyssinica Warb. × D. hebecarpa Warb.).; Results: The best SSC prediction model was developed with PLS regression (root mean square error of prediction (RMSEP ) of 0.71 °Brix, prediction data set (RP2 ) of 0.74 and residual predictive deviation (RPD) of 2.82). Although interval PLS was tested, genetic algorithm PLS performed better for TA (RMSEP of 4.8 g kg-1 , RP2 of 0.40, and RPD of 1.67), and for pH (RMSEP of 0.03, RP2 of 0.90, and RPD of 6.67).; Conclusion: NIRS can be used as a non-destructive method to determine quality parameters in intact dovyalis hybrid fruit. © 2018 Society of Chemical Industry.; © 2018 Society of Chemical Industry.

Abstract: The objective of this work was to establish physical and chemical characterizations of dovyalis hybrid fruits (Dovyalis abyssinica and D. hebecarpa). Samples of 25 fruits were characterized by evaluation of length and width, weight, percentage and number of seeds per fruit, peel percentage, pulp percentage, total soluble solids (TSS), titratable acidity (TA), vitamin C and TSS/TA ratio. Dovyalis fruit has good physical quality for market with an average of 75% pulp. Vitamin C content averaged 120.3 mg/100 g of fresh fruit, characterizing dovyalis as a good source of vitamin C.

Abstract: The objective of this work was to evaluate the bioactive compounds, antioxidant activity, and physicochemical characteristics of dovyalis fruit to obtain technological knowledge about this fruit when grown under the conditions found in the municipality of Marechal Cândido Rondon, Parana State, Brazil. Dovyalis fruits from the State University of Western Parana, which was established in 2012, were harvested in March 2016. Dovyalis fruits were collected from several plants and were divided among three lots. After the harvest, were immediately taken to the Post-Harvest Laboratory for evaluation of the antioxidant activity by the DPPH, ABTS and FRAP methods. The physicochemical characteristics of the fruits and the total phenolic compounds, flavonoids, ascorbic acid, anthocyanins, respiration, and fruit color were evaluated. The experimental design was completely randomized, with the study containing three groups and three replicates per group. Dovyalis fruits present high antioxidant capacity and are characterized as acidic fruits, due to the high FRAP activity. Dovyalis fruits have a very attractive color and high acidity, which makes them appropriate for processing. Regarding the antioxidant activity present in the fruit, the most bioactive components are flavonoids and anthocyanins. High ascorbic acid content was observed in mature dovyalis fruits. Dovyalis fruits are considered climacteric.