About: Constant phase element is a research topic. Over the lifetime, 853 publications have been published within this topic receiving 26752 citations.
TL;DR: In this article, it was shown that the electrical double-layer at a solid electrode does not in general behave as a pure capacitance but rather as an impedance displaying a frequency-independent phase angle different from 90°.
TL;DR: In this article, a new linear capacitor model is proposed based on Curie's empirical law of 1889, which states that the current through a capacitor is i(t)=U/sub 0/(h/sub 1/t/sup n/), where h is the dc voltage applied at t = 0, and 0 > 0.
Abstract: A new linear capacitor model is proposed. It is based on Curie's empirical law of 1889 which states that the current through a capacitor is i(t)=U/sub 0//(h/sub 1/t/sup n/), where h/sub 1/ and n are constants, U/sub 0/ is the dc voltage applied at t=0, and 0 >
TL;DR: Hirschorn et al. as mentioned in this paper proposed a method to solve the problem of chemical engineering by using the theory of theory of I.I. Theory Bryan Hirschorn,* Mark E. Orazem,** Bernard Tribollet,** Vincent Vivier,** Isabelle Frateur, and Marco Musiani.
Abstract: I. Theory Bryan Hirschorn,* Mark E. Orazem,** Bernard Tribollet,** Vincent Vivier,*** Isabelle Frateur, and Marco Musiani*** Department of Chemical Engineering, University of Florida, Gainesville, Florida 32611, USA Laboratoire Interfaces et Systemes Electrochimiques, UPR 15 du CNRS, Université Pierre et Marie Curie, 75252 Paris cedex 05, France Laboratoire de Physico-Chimie des Surfaces, UMR CNRS-ENSCP 7045, Ecole Nationale Supérieure de Chimie de Paris, Chimie ParisTech, 75005 Paris, France Istituto per l’Energetica e le Interfasi, Consiglio Nazionale delle Ricerche, 35127 Padova, Italy
TL;DR: In this paper, it was shown that an electrode with a double layer of CPE character can never be an ''ideally polarizable electrode'' and the conclusions can be qualitatively applied to all systems with an interface revealing CPE behaviour.