TL;DR: In this paper, a kinetic theory approach to collision processes in ionized and neutral gases is presented, which is adequate for the unified treatment of the dynamic properties of gases over a continuous range of pressures from the Knudsen limit to the high pressure limit where the aerodynamic equations are valid.
Abstract: A kinetic theory approach to collision processes in ionized and neutral gases is presented. This approach is adequate for the unified treatment of the dynamic properties of gases over a continuous range of pressures from the Knudsen limit to the high-pressure limit where the aerodynamic equations are valid. It is also possible to satisfy the correct microscopic boundary conditions. The method consists in altering the collision terms in the Boltzmann equation. The modified collision terms are constructed so that each collision conserves particle number, momentum, and energy; other characteristics such as persistence of velocities and angular dependence may be included. The present article illustrates the technique for a simple model involving the assumption of a collision time independent of velocity; this model is applied to the study of small amplitude oscillations of one-component ionized and neutral gases. The initial value problem for unbounded space is solved by performing a Fourier transformation on the space variables and a Laplace transformation on the time variable. For uncharged gases there results the correct adiabatic limiting law for sound-wave propagation at high pressures and, in addition, one obtains a theory of absorption and dispersion of sound for arbitrary pressures. For ionized gases the difference in the nature of the organization in the low-pressure plasma oscillations and in high-pressure sound-type oscillations is studied. Two important cases are distinguished. If the wavelengths of the oscillations are long compared to either the Debye length or the mean free path, a small change in frequency is obtained as the collision frequency varies from zero to infinity. The accompanying absorption is small; it reaches its maximum value when the collision frequency equals the plasma frequency. The second case refers to waves shorter than both the Debye length and the mean free path; these waves are characterized by a very heavy absorption.
TL;DR: In this paper, the rate of inter-particle collisions as a function of the turbulence parameters and particle properties is investigated. But the authors focus on the effect of particle decorrelation and preferential concentration on the collision frequency.
Abstract: Direct numerical simulations of heavy particles suspended in a turbulent fluid are performed to study the rate of inter-particle collisions as a function of the turbulence parameters and particle properties. The particle volume fractions are kept small (∼10−4) so that the system is well within the dilute limit. The fluid velocities are updated using a pseudo-spectral algorithm while the particle forces are approximated by Stokes drag. One unique aspect of the present simulations is that the particles have finite volumes (as opposed to point masses) and therefore particle collisions must be accounted for. The collision frequency is monitored over several eddy turnover times. It is found that particles with small Stokes numbers behave similarly to the prediction of Saffman & Turner (1956). On the other hand, particles with very large Stokes numbers have collision frequencies similar to kinetic theory (Abrahamson 1975). For intermediate Stokes numbers, the behaviour is complicated by two effects: (i) particles tend to collect in regions of low vorticity (high strain) due to a centrifugal effect (preferential concentration); (ii) particle pairs are less strongly correlated with each other, resulting in an increase in their relative velocity. Both effects tend to increase collision rates, however the scalings of the two effects are different, leading to the observed complex behaviour. An explanation for the entire range of Stokes numbers can be found by considering the relationship between the collision frequency and two statistical properties of the particle phase: the radial distribution function and the relative velocity probability density function. Statistical analysis of the data, in the context of this relationship, confirms the relationship and provides a quantitative description of how preferential concentration and particle decorrelation ultimately affect the collision frequency.
TL;DR: In this paper, the authors reviewed the solutions to the kinetic equation of coagulation from the standpoint of their asymptotic behavior, and showed that the shape of the self-preserving spectrum is greatly influenced by the form of the collision frequency factor.
TL;DR: In this paper, it was shown that the widely used equilibrium in which the nighttime F region is supported by E×B drifts is unstable if, in addition to the supporting eastward field, a north-south electric field component exists.
Abstract: It is shown that the widely used equilibrium in which the nighttime F region is supported by E×B drifts is unstable if, in addition to the supporting eastward field, a north-south electric field component exists. The instability, which takes the form of rising and falling sheets of ionization, has a growth rate γ ≈ 3 × 10−4 νin−1 sec−1, where νin is ion-neutral collision frequency at the F region peak. These conclusions are based on a set of new moment equations that govern the time evolution of the Pedersen conductance and the plasma content of a flux tube. It is argued that temperate- and high-latitude spread F are a result of this instability. The new moment equations also predict: (1) that there is a maximum height-integrated Pedersen current that the F region can carry; and (2) that barium clouds deform in agreement with observations of recent releases.
TL;DR: The study of single NP collisions allows one to screen particle size distributions and estimate NP concentrations and diffusion coefficients and indicates that the collision of NPs at the detector electrodes occurs in a statistically random manner, with the average frequency a function of particle concentration and diffusion coefficient.
Abstract: Electrochemical hydrazine oxidation and proton reduction occur at a significantly higher rate at Pt than at Au or C electrodes. Thus, the collision and adhesion of a Pt particle on a less active Au or C electrode leads to a large current amplification by electrocatalysis at single nanoparticles (NPs). At low particle concentrations, the collision of Pt NPs was characterized by current transients composed of individual current profiles that rapidly attained a steady state, signaling single NP collisions. The characteristic steady-state current was used to estimate the particle size. The fluctuation in collision frequency with time indicates that the collision of NPs at the detector electrodes occurs in a statistically random manner, with the average frequency a function of particle concentration and diffusion coefficient. A longer term current decay in single current transients, as opposed to the expected steady-state behavior, was more pronounced for proton reduction than for hydrazine oxidation, revealing microscopic details of the nature of the particle interaction with the detector electrode and the kinetics of electrocatalysis at single NPs. The study of single NP collisions allows one to screen particle size distributions and estimate NP concentrations and diffusion coefficients.