TL;DR: The composition of the Skaergaard magma has been determined experimentally for various stages of its evolution, and these compositions are consistent with revised volumetric and compositional data for the individual units of the intrusion.
Abstract: Re-examination of the Skaergaard intrusion of East Greenland has revealed that the model of differentiation based on an original liquid with the composition of the chilled margin and a large hidden zone is no longer tenable. The composition of the Skaergaard magma has been determined experimentally for various stages of its evolution, and these compositions are consistent with revised volumetric and compositional data for the individual units of the intrusion. In its later stages, the magma separated into two immiscible liquids, one rich in iron and phosphorus and the other rich in silica and alkalis.
TL;DR: The Sept Iles layered intrusion (Quebec, Canada; 564 Ma) is a large plutonic body with a diameter of 80 km and a thickness of 6 km made up from its base to top of a layered series with troctolite and gabbro, and an upper border series with anorthosite, capped by cupolas of A-type granite.
TL;DR: In this article, the authors used the MELTS thermodynamic calculator combined with equations predicting mineral-melt equilibria from experiments on tholeiitic basalts, indicate that basaltic to monzonitic melt compositions are in equilibrium with the troctolites and gabbros of the Layered Series.
Abstract: The undeformed 564 Ma Sept Iles layered intrusion (Quebec, Canada) is a large igneous body of c. 20 000 km
3
. From the base to the top, it consists of a Layered Series dominated by troctolite and gabbro, an anorthositic Upper Border Series and a dominantly granitic Upper Series. The parent magma of the Layered Series is inferred to be an iron-rich tholeiitic basalt (48 wt % SiO
2
; 15 wt % FeO
t
). Whole-rock compositions from the chilled margin, dykes cross-cutting the Layered Series and silicic rocks from the Upper Series display continuous major and trace element geochemical trends ranging from basalts to ferroan metaluminous A-type granites (77 wt % SiO
2
). Initial 143
Nd/
144
Nd (0·51201–0·51207) and 87
Sr/
86
Sr (0·70353–0·70548) indicate a juvenile-mantle source and minimal contamination by old crust (1–2%) during crystallization. Geochemical modeling, using the MELTS thermodynamic calculator combined with equations predicting mineral–melt equilibria from experiments on tholeiitic basalts, indicate that basaltic to monzonitic melt compositions are in equilibrium with the troctolites and gabbros of the Layered Series. Fe–Ti oxides saturate early in the Layered Series, after 14% fractionation of plagioclase–olivine cumulates. Further fractionation of Fe–Ti oxide-bearing gabbros drives the residual liquids toward silica enrichment and iron depletion. Major and trace element modeling indicates that the A-type granites from the Upper Series were produced by protracted fractional crystallization of an iron-rich basaltic parent magma, at a fraction of residual liquid of only 8%. The observed relative volumes of mafic cumulates and silicic rocks in the intrusion are in agreement with the calculations. Most of the intermediate compositions correspond to magmatic mafic enclave-bearing granitoids and display geochemical evidence of hybridization. Intermediate compositions produced by fractional crystallization are scarce and a Daly gap occurs from 57 to 67 wt % SiO
2
. This gap could result either from the fractional crystallization process or from silicate–liquid immiscibility during that compositional interval.
TL;DR: In this article, the chemistry of the Skaergaard initial magma has been investigated using computer least squares and Rayleigh fractionation modeling, showing that the only important cumulus phases at this stage were olivine and plagioclase but clmopyroxene grew by heteradcumulus growth and effectively eliminated all intercumulus liquid.
TL;DR: In this paper, a variety of rock types are developed in the Shonkin Sag laccolith, with extreme compositions represented by the porphyritic pseudoleucite-bearing chilled margin, shonkinitic in composition, and by the final differentiate, chemically a nepheline syenite.
Abstract: A variety of rock types is developed in the Shonkin Sag laccolith, with extreme compositions represented by the porphyritic pseudoleucite-bearing chilled margin, shonkinitic in composition, and by the final differentiate, chemically a nepheline syenite During differentiation the pyroxenes changed in composition from Ca-rich varieties through aegirine-augite to acmite; there is no evidence of an immiscibility gap between Ca-rich and Na-rich pyroxenes Olivine compositions changed from approximately Fa20 to Fa40, but in marked contrast the coexisting biotites exhibit a more extensive compositional range, from annite24 to annite100; the crystal margins of annites in the most evolved rocks are manganophyllite-rich Titanomagnetites are TiO2-poor varieties Arfvedsonite and melanite occur in the most evolved syenites