Topic
Binary acid
About: Binary acid is a research topic. Over the lifetime, 82 publications have been published within this topic receiving 984 citations. The topic is also known as: hydracid & hydroacid.
Papers published on a yearly basis
Papers
TL;DR: A unique binary chiral phosphoric acid 1a/MgF(2) catalyst that enables effective catalysis of asymmetric Friedel-Crafts reactions of phenols with up to 82% yield and >99% ee is presented.
138 citations
TL;DR: A new asymmetric binary acid catalyst was developed to promote 1,5-H transfer specifically and stereoselectively in tert-aminocyclization reactions with excellent activity, high enantioselectivity, and broad substrate scope.
Abstract: Selective H transfer by ABC: A new asymmetric binary acid catalyst was developed to promote 1,5-H transfer specifically and stereoselectively in tert-aminocyclization reactions with excellent activity, high enantioselectivity, and broad substrate scope. The H atom (in red) was proven to transfer through a stereospecific suprafacial pathway (see scheme).
130 citations
TL;DR: The authors' endeavors in developing asymmetric binary acid catalysis are summarized in this feature article.
104 citations
TL;DR: The authors showed that swapping the anions of an indium Lewis acid leads to a remarkable regioselectivity switch between asymmetric 1,2-and 1,4-addition reactions of N-protected indoles (II) and β,γ-unsaturated α-keto esters (III).
Abstract: Swapping the anions of an indium Lewis acid leads to a remarkable regioselectivity switch between asymmetric 1,2- and 1,4-addition reactions of N-protected indoles (II) and β,γ-unsaturated α-keto esters (III).
104 citations
TL;DR: The exchange of the metal ion from In(III to Sc(III) in a binary acid catalyst leads to a switch in the diastereoselectivity of [4 + 2] cycloadditions as discussed by the authors.
Abstract: The exchange of the metal ion from In(III) to Sc(III) in a binary acid catalyst leads to a switch in the diastereoselectivity of [4 + 2] cycloadditions.
86 citations
Related Topics (5)
Performance Metrics
| Year | Papers |
|---|---|
| 2021 | 2 |
| 2020 | 1 |
| 2019 | 6 |
| 2018 | 1 |
| 2017 | 3 |
| 2016 | 6 |