TL;DR: In the Lachlan Fold Belt of southeastern Australia, Upper Devonian A-type granite suites were emplaced after the Lower Devonian I-type granites of the Bega Batholith as mentioned in this paper.
Abstract: In the Lachlan Fold Belt of southeastern Australia, Upper Devonian A-type granite suites were emplaced after the Lower Devonian I-type granites of the Bega Batholith. Individual plutons of two A-type suites are homogeneous and the granites are characterized by late interstitial annite. Chemically they are distinguished from I-type granites with similar SiO2 contents of the Bega Batholith, by higher abundances of large highly charged cations such as Nb, Ga, Y, and the REE and lower Al, Mg and Ca: high Ga/Al is diagnostic. These A-type suites are metaluminous, but peralkaline and peraluminous A-type granites also occur in Australia and elsewhere. Partial melting of felsic granulite is the preferred genetic model. This source rock is the residue remaining in the lower crust after production of a previous granite. High temperature, vapour-absent melting of the granulitic source generates a low viscosity, relatively anhydrous melt containing F and possibly Cl. The framework structure of this melt is considerably distorted by the presence of these dissolved halides allowing the large highly charged cations to form stable high co-ordination structures. The high concentration of Zr and probably other elements such as the REE in peralkaline or near peralkaline A-type melts is a result of the counter ion effect where excess alkali cations stabilize structures in the melt such as alkali-zircono-silicates. The melt structure determines the trace element composition of the granite. Separation of a fluid phase from an A-type magma results in destabilization of co-ordination complexes and in the formation of rare-metal deposits commonly associated with fluorite. At this stage the role of Cl in metal transport is considered more important than F.
TL;DR: In this article, the authors studied the effect of pre-emptive and preemptive gradients in T and O 2 in a variety of compositionally zoned ash flow tuffs.
Abstract: Every large eruption of nonbasaltic magma taps a magma reservoir that is thermally and compositionally zoned. Most small eruptions also tap parts of heterogeneous and evolving magmatic systems. Several kinds of compositionally zoned ash flow tuffs provide examples of preemptive gradients in T and ƒO2, in chemical and isotopic composition, and in the variety, abundance, and composition of phenocrysts. Such gradients help to constrain the mechanisms of magmatic differentiation operating in each system. Roofward decreases in both T and phenocryst content suggest water concentration gradients in magma chambers. Wide compositional gaps are common features of large eruptions, proving the existence of such gaps in a variety of magmatic systems. Nearly all magmatic systems are ‘fundamentally basaltic’ in the sense that mantle-derived magmas supply heat and mass to crustal systems that evolve a variety of compositional ranges. Feedback between crustal melting and interception of basaltic intrusions focuses and amplifies magmatic anomalies, suppresses basaltic volcanism, produces and sustains crustal magma chambers, and sometimes culminates in large-scale diapirism. Degassing of basalt crystallizing in the roots of these systems provides a flux of He, CO2, S, halogens, and other components, some of which may influence chemical transport in the overlying, more silicic zones. Basaltic magmas become andesitic by concurrent fractionation and assimilation of partial melts over a large depth range during protracted upward percolation in a plexus of crustal conduits. Zonation in the andesitic-dacitic compositional range develops subsequently within magma chambers, primarily by crystal fractionation. Some dacitic and rhyolitic liquids may separate from less-silicic parents by means of ascending boundary layers along the walls of convecting magma chambers. Many rhyolites, however, are direct partial melts of crustal rocks, and still others fractionate from crystal-rich intermediate parents. The zoning of rhyolitic magma is accomplished predominantly by liquid state thermodiffusion and volatile complexing; liquid structural gradients may be important, and thermal gradients across magma chamber boundary layers are critical. Intracontinental silicic batholiths form where extensional tectonism favors coalescence of crustal partial melts instead of hybridization with the intrusive basaltic magma. Cordilleran batholiths, however, result from prolonged diffuse injection of the crust by basalt that hybridizes, fractionates, and preheats the crust with pervasive mafic to intermediate forerunners, culminating in large-scale diapiric mobilization of partially molten zones from which granodioritic magmas separate. Much of the variability among magmatic systems probably reflects the depth variation of relative rates of transport of magma, heat, and volatile components, as controlled in turn by the orientation and relative magnitudes of principal stresses in the lithosphere, the thickness and composition of the affected crust, and variations in the rate and longevity of basaltic magma supply. Extension of the lithosphere may reduce the susceptibility of basaltic magmas to hybridization in the crust, but it can also enhance the role of mantle-derived volatiles in chemical transport.
TL;DR: A-type granites have long been recognized as a distinct group of granites, the term A-type was coined first less than thirty years ago as discussed by the authors, and they are fairly common at shallower depths, especially at the subvolcanic level where they form ring complexes rooting caldera volcanoes.
TL;DR: In this paper, the authors show that the concentration of Nd correlates well with eNd in the batholith rocks and support the conclusion that juvenile continental crust is derived from mantle reservoirs that are depleted in incompatible elements.
Abstract: Plutonic igneous rocks of the Sierra Nevada batholith exhibit a range of Nd isotopic composition described by eNd = +6.5 to −7.6. Similar rock types from the Peninsular Ranges have eNd = +8.0 to −6.4. In both batholiths, eNd correlates strongly with initial 87Sr/86Sr. Decreasing eNd values are accompanied by increasing 87Sr/86Sr and increasing δ18O; the correlation with δ18O being more pronounced for the Peninsular Ranges. The eNd values show regular geographic variations, as was found previously for initial 87Sr/86Sr. Three metasedimentary country rock samples from the Sierra Nevada region have low eNd values (−11 to −16) and Precambrian model Sm-Nd ages (1.5 to 1.9 AE). The country rock eNd values, and those of primitive oceanic island arcs (eNd = +8), bracket the data for the batholith rocks. The Nd, Sr, and O isotopic data can be explained if the batholiths are mixtures of island arc and metasedimentary components, the latter being of both Paleozoic and early Proterozoic age. This model appears to be consistent with existing Pb isotopic data. Consideration of O-Sr isotopic relations and the variation of 147Sm/144Nd with eNd suggests that assimilation of crustal rocks by magmas rising from the mantle and undergoing fractional crystallization could have been the major process responsible for the mixing of crustal- and mantle-derived components. The isotopic data, when combined with assumptions about the structure of the crust beneath the batholiths, suggest that about 50% of the crustal material presently within the geographic boundaries of the batholiths and above the Moho represents juvenile crust derived from the mantle in the Mesozoic. The remaining material appears to be mostly derived from 1.8-AE crust, yielding an average crust formation age of nearly 1 AE for this section of the crust. This result, which may apply to large portions of the Cordillera, suggests that the average age of the North American continent may be greater than previously estimated. The concentration of Nd correlates well with eNd in the batholith rocks and supports the conclusion that juvenile continental crust is derived from mantle reservoirs that are depleted in incompatible elements. A 1.5-AE Sm-Nd model age for sedimentary rocks of the Mesozoic(?) Calaveras Formation indicates that the Nd in this “oceanic” terrain is dominated by continental detritus and demonstrates the potential of Sm-Nd isotopic studies for aiding in construction of tectonic models.