About: Atrane is a research topic. Over the lifetime, 138 publications have been published within this topic receiving 2682 citations. The topic is also known as: atranes.
TL;DR: A review of chemical reactivities and structural properties of main group atrane systems are surveyed in this paper, where the bridgehead-bridgehead bond length lies between the sum of the van der Waals radii and a normal transannular bond.
TL;DR: In this paper, a simple and versatile technique to obtain mesoporous oxides is presented, where the original chemical contribution of this approach lies in the use of atrane complexes as precursors.
TL;DR: Porous pure and doped silicas with pore sizes at two length scales (meso/macroporous) were prepared and shaped both as powders and monoliths through a one-pot surfactant assisted procedure by using a simple template agent and starting from atrane complexes as inorganic precursors as discussed by the authors.
TL;DR: In this paper, the stable azide adduct MeN 3 P(MeNCH 2 CH 2 ) 3 N (8), and [HRNP(NMe 2 ] (CF 3 CO 2 ) (R=Ph, 5(CF 3 Co 2 ); R=Me, 6(CF3 Co 2 )), [MePhNP(Me NCH 2CH 2 ] 3 N]I (7(I)), the syntheses of MeN
Abstract: The syntheses of MeN=P(MeNCH 2 CH 2 ) 3 N (4), [HRNP(MeNCH 2 CH 2 ) 3 N] (CF 3 CO 2 ) (R=Ph, 5(CF 3 CO 2 ); R=Me, 6(CF 3 CO 2 )), [MePhNP(MeNCH 2 CH 2 ) 3 N]I (7(I)), the stable azide adduct MeN 3 P(MeNCH 2 CH 2 ) 3 N (8), and [HRNP(NMe 2 ) 3 ] (CF 3 CO 2 ) (R=Ph, 9(CF 3 CO 2 ) are reported