TL;DR: In this paper, the alpha effect was surveyed in the context of possible explanations for this phenomenon and four factors (ground-state destabilization of the nucleophile, transition-state stabilization, solvent effect differences for alpha and non-alpha nucleophiles, and product stability) may be involved in contributory roles.
Abstract: Instances of high reactivity (as signaled by a positive Bronsted deviation) by nucleophiles bearing one or more unshared pairs of electrons on an atom adjacent to the nucleophilic center (the alpha effect) are surveyed in the context of possible explanations for this phenomenon. No single cause appears to account satisfactorily for all the data. However, four factors (ground-state destabilization of the nucleophile, transition-state stabilization, solvent effect differences for alpha and nonalpha nucleophiles, and product stability) may be involved in contributory roles. The response to proton basicity of a substrate is probably not related to its susceptibility to the alpha effect. Carbon electrophiles seem to be receptive to the alpha effect in the order digonal > trigonal > tetrahedral. The inconsistent behavior of alpha nucleophiles makes the prediction of alpha effects rather risky and confirms the complicated nature of nucleophilic substitutions.
TL;DR: In this article, it was shown that isotropic helical turbulence leads to an alpha effect and a turbulent diffusivity whose values are independent of the magnetic Reynolds number, provided the value of the Reynolds number exceeds unity.
Abstract: Using numerical simulations at moderate magnetic Reynolds numbers up to 220 it is shown that in the kinematic regime, isotropic helical turbulence leads to an alpha effect and a turbulent diffusivity whose values are independent of the magnetic Reynolds number, $\Rm$, provided $\Rm$ exceeds unity. These turbulent coefficients are also consistent with expectations from the first order smoothing approximation. For small values of $\Rm$, alpha and turbulent diffusivity are proportional to $\Rm$. Over finite time intervals meaningful values of alpha and turbulent diffusivity can be obtained even when there is small-scale dynamo action that produces strong magnetic fluctuations. This suggests that small-scale dynamo-generated fields do not make a correlated contribution to the mean electromotive force.
TL;DR: In this paper, the effect of a dynamo-generated mean magnetic field of Beltrami type on the mean electromotive force was studied, where the tensor components were characterized by a pseudoscalar alpha and a scalar turbulent magnetic diffusivity etat.
Abstract: The effect of a dynamo-generated mean magnetic field of Beltrami type on the mean electromotive force is studied. In the absence of the mean magnetic field the turbulence is assumed to be homogeneous and isotropic, but it becomes inhomogeneous and anisotropic with this field. Using the testfield method the dependence of the alpha and turbulent diffusivity tensors on the magnetic Reynolds number Rm is determined for magnetic fields that have reached approximate equipartition with the velocity field. The tensor components are characterized by a pseudoscalar alpha and a scalar turbulent magnetic diffusivity etat. Increasing Rm from 2 to 600 reduces etat by a factor ~5, suggesting that the quenching of etat is, in contrast to the 2-dimensional case, only weakly dependent on Rm. Over the same range of Rm, however, alpha is reduced by a factor ~14, which can qualitatively be explained by a corresponding increase of a magnetic contribution to the alpha effect with opposite sign. The level of fluctuations of alpha and etat is only 10% and 20% of the respective kinematic reference values.
TL;DR: It seems that there is no clear relation between alpha and the helicity of the flow, contrary to what is often assumed for the parametrization of mean-field dynamo models.
Abstract: We perform numerical experiments to calculate the kinematic {alpha} effect for a family of maximally helical, chaotic flows with a range of correlation times. We find that the value of {alpha} depends on the structure of the flow, on its correlation time and on the magnetic Reynolds number in a nontrivial way. Furthermore, it seems that there is no clear relation between {alpha} and the helicity of the flow, contrary to what is often assumed for the parametrization of mean-field dynamo models.