Abstract: We report on the elastocaloric effect of a superelastic Ni-Ti wire to be used in a cooling device. Initially, each evaluated wire was subjected to 400 loading/unloading training cycles in order to stabilize its superelastic behavior. The wires were trained at different temperatures, which lead to different stabilized superelastic behaviors. The stabilized (trained) wires were further tested isothermally (at low strain-rate) and adiabatically (at high strain-rate) at different temperatures (from 312 K to 342 K). We studied the impact of the training temperature and resulting superelastic behavior on the adiabatic temperature changes. The largest measured adiabatic temperature change during loading was 25 K with a corresponding 21 K change during unloading (at 322 K). A special focus was put on the irreversibilities in the adiabatic temperature changes between loading and unloading. It was shown that there are two sources of the temperature irreversibilities: the hysteresis (and related entropy generation) and the temporary residual strain immediately after unloading, respectively. The latter results in the temporary bending of the wire and reduced negative adiabatic temperature change. The paper also shows the impact of the applied strain on the adiabatic temperature changes as well as the distribution of the elastocaloric effect over the wire during loading in the case of two wires trained at different temperatures and the virgin wire, respectively. In the end, we propose guidelines about the required material properties for an efficient elastocaloric cooling device.

Abstract: The appearance of so-called exceptional points in the complex spectra of non-Hermitian systems is often associated with phenomena that contradict our physical intuition. One example of particular interest is the state-exchange process predicted for an adiabatic encircling of an exceptional point. In this work we analyze this and related processes for the generic system of two coupled oscillator modes with loss or gain. We identify a characteristic system evolution consisting of periods of quasistationarity interrupted by abrupt nonadiabatic transitions and we present a qualitative and quantitative description of this switching behavior by connecting the problem to the phenomenon of stability loss delay. This approach makes accurate predictions for the breakdown of the adiabatic theorem as well as the occurrence of chiral behavior observed previously in this context and provides a general framework to model and understand quasiadiabatic dynamical effects in non-Hermitian systems.

Abstract: The renormalization of electronic eigenenergies due to electron-phonon coupling (temperature dependence and zero-point motion effect) is sizable in many materials with light atoms. This effect, often neglected in ab initio calculations, can be computed using the perturbation-based Allen-Heine-Cardona theory in the adiabatic or non-adiabatic harmonic approximation. After a short description of the recent progresses in this field and a brief overview of the theory, we focus on the issue of phonon wavevector sampling convergence, until now poorly understood. Indeed, the renormalization is obtained numerically through a slowly converging q-point integration. For non-zero Born effective charges, we show that a divergence appears in the electron-phonon matrix elements at q → Γ, leading to a divergence of the adiabatic renormalization at band extrema. This problem is exacerbated by the slow convergence of Born effective charges with electronic wavevector sampling, which leaves residual Born effective charges in ab initio calculations on materials that are physically devoid of such charges. Here, we propose a solution that improves this convergence. However, for materials where Born effective charges are physically non-zero, the divergence of the renormalization indicates a breakdown of the adiabatic harmonic approximation, which we assess here by switching to the non-adiabatic harmonic approximation. Also, we study the convergence behavior of the renormalization and develop reliable extrapolation schemes to obtain the converged results. Finally, the adiabatic and non-adiabatic theories, with corrections for the slow Born effective charge convergence problem (and the associated divergence) are applied to the study of five semiconductors and insulators: α-AlN, β-AlN, BN, diamond, and silicon. For these five materials, we present the zero-point renormalization, temperature dependence, phonon-induced lifetime broadening, and the renormalized electronic band structure.

Abstract: We show how to apply the quantum adiabatic algorithm directly to the quantum computation of molecular properties. We describe a procedure to map electronic structure Hamiltonians to 2-body qubit Hamiltonians with a small set of physically realizable couplings. By combining the Bravyi-Kitaev construction to map fermions to qubits with perturbative gadgets to reduce the Hamiltonian to 2-body, we obtain precision requirements on the coupling strengths and a number of ancilla qubits that scale polynomially in the problem size. Hence our mapping is efficient. The required set of controllable interactions includes only two types of interaction beyond the Ising interactions required to apply the quantum adiabatic algorithm to combinatorial optimization problems. Our mapping may also be of interest to chemists directly as it defines a dictionary from electronic structure to spin Hamiltonians with physical interactions.

Abstract: All cosmological observations to date are consistent with adiabatic, Gaussian and nearly scale invariant initial conditions. These findings provide strong evidence for a particular symmetry breaking pattern in the very early universe (with a close to vanishing order parameter, $\epsilon$), widely accepted as conforming to the predictions of the simplest realizations of the inflationary paradigm. However, given that our observations are only privy to perturbations, in inferring something about the background that gave rise to them, it should be clear that many different underlying constructions project onto the same set of cosmological observables. Features in the primordial correlation functions, if present, would offer a unique and discriminating window onto the parent theory in which the mechanism that generated the initial conditions is embedded. In certain contexts, simple linear response theory allows us to infer new characteristic scales from the presence of features that can break the aforementioned degeneracies among different background models, and in some cases can even offer a limited spectroscopy of the heavier degrees of freedom that couple to the inflaton. In this review, we offer a pedagogical survey of the diverse, theoretically well grounded mechanisms which can imprint features into primordial correlation functions in addition to reviewing the techniques one can employ to probe observations. These observations include cosmic microwave background anisotropies and spectral distortions as well as the matter two and three point functions as inferred from large-scale structure and potentially, 21 cm surveys.

Abstract: A generalization of the Aubry-Andr\'e-Harper (AAH) model is developed, containing a tunable phase shift between on-site and off-diagonal modulations. A localization transition can be induced by varying just this phase, keeping all other model parameters constant. The complete localization phase diagram is obtained. Unlike the original AAH model, the generalized model can exhibit a transition between topologically trivial band structures and topologically nontrivial band structures containing protected boundary states. These boundary states can be pumped across the system by adiabatic variations in the phase shift parameter. The model can also be used to demonstrate the phenomenon of adiabatic pumping breakdown due to localization.

Abstract: Adiabatic demagnetization is currently gaining strong interest in searching for alternatives to (3)He-based refrigeration techniques for achieving temperatures below 2 K. The main reasons for that are the recent shortage and high price of the rare helium isotope (3)He. Here we report the discovery of a large magnetocaloric effect in the intermetallic compound YbPt2Sn, which allows adiabatic demagnetization cooling from 2 K down to 0.2 K. We demonstrate this with a home-made refrigerator. Other materials, for example, paramagnetic salts, are commonly used for the same purpose but none of them is metallic, a severe limitation for low-temperature applications. YbPt2Sn is a good metal with an extremely rare weak magnetic coupling between the Yb atoms, which prevents them from ordering above 0.25 K, leaving enough entropy free for use in adiabatic demagnetization cooling. The large volumetric entropy capacity of YbPt2Sn guarantees also a good cooling power.

Abstract: We provide a complete solution to hydrodynamic transport at all orders in the gradient expansion compatible with the second law constraint. The key new ingredient we introduce is the notion of adiabaticity, which allows us to take hydrodynamics off-shell. Adiabatic fluids are such that off-shell dynamics of the fluid compensates for entropy production. The space of adiabatic fluids is quite rich, and admits a decomposition into seven distinct classes. Together with the dissipative class this establishes the eightfold way of hydrodynamic transport. Furthermore, recent results guarantee that dissipative terms beyond leading order in the gradient expansion are agnostic of the second law. While this completes a transport taxonomy, we go on to argue for a new symmetry principle, an Abelian gauge invariance that guarantees adiabaticity in hydrodynamics. We suggest that this symmetry is the macroscopic manifestation of the microscopic KMS invariance. We demonstrate its utility by explicitly constructing effective actions for adiabatic transport. The theory of adiabatic fluids, we speculate, provides a useful starting point for a new framework to describe non-equilibrium dynamics, wherein dissipative effects arise by Higgsing the Abelian symmetry.

Abstract: Hydrodynamics is the low-energy effective field theory of any interacting quantum theory, capturing the long-wavelength fluctuations of an equilibrium Gibbs densitymatrix. Conventionally, one views the effective dynamics in terms of the conserved currents, which should be expressed via the constitutive relations in terms of the fluid velocity and the intensive parameters such as the temperature, chemical potential, etc. . . However, not all constitutive relations are acceptable; one has to ensure that the second law of thermodynamics is satisfied on all physical configurations. In this paper, we provide a complete solution to hydrodynamic transport at all orders in the gradient expansion compatible with the second law constraint. The key new ingredient we introduce is the notion of adiabaticity, which allows us to take hydrodynamics off-shell. Adiabatic fluids are such that off-shell dynamics of the fluid compensates for entropy production. The space of adiabatic fluids is quite rich, and admits a decomposition into seven distinct classes. Together with the dissipative class this establishes the eightfold way of hydrodynamic transport. Furthermore, recent results guarantee that dissipative terms beyond leading order in the gradient expansion are agnostic of the second law. While this completes a transport taxonomy, we go on to argue for a new symmetry principle, an Abelian gauge invariance that guarantees adiabaticity in hydrodynamics. We suggest that this symmetry is the macroscopic manifestation of the microscopic KMS invariance. We demonstrate its utility by explicitly constructing effective actions for adiabatic transport. The theory of adiabatic fluids, we speculate, provides a useful starting point for a new framework to describe non-equilibrium dynamics, wherein dissipative effects arise by Higgsing the Abelian symmetry.

Abstract: Adiabatic state engineering is a powerful technique in quantum information and quantum control. However, its performance is limited by the adiabatic theorem of quantum mechanics. In this scenario, shortcuts to adiabaticity, such as provided by the superadiabatic theory, constitute a valuable tool to speed up the adiabatic quantum behavior. Here, we propose a superadiabatic route to implement universal quantum computation. Our method is based on the realization of piecewise controlled superadiabatic evolutions. Remarkably, they can be obtained by simple time-independent counter-diabatic Hamiltonians. In particular, we discuss the implementation of fast rotation gates and arbitrary n-qubit controlled gates, which can be used to design different sets of universal quantum gates. Concerning the energy cost of the superadiabatic implementation, we show that it is dictated by the quantum speed limit, providing an upper bound for the corresponding adiabatic counterparts.

Abstract: Context. The CoRoT and Kepler space-borne missions have provided us with a wealth of high-quality observational data that allows for seismic inferences of stellar interiors. This requires the computation of precise and accurate theoretical frequencies, but imperfect modeling of the uppermost stellar layers introduces systematic errors. To overcome this problem, an empirical correction has been introduced by Kjeldsen et al. (2008, ApJ, 683, L175) and is now commonly used for seismic inferences. Nevertheless, we still lack a physical justification allowing for the quantification of the surface-effect corrections. Aims. Our aim is to constrain the surface-effect corrections across the Hertzsprung-Russell (HR) diagram using a set of 3D hydrodynamical simulations. Methods. We used a grid of these simulations computed with the CO 5 BOLD code to model the outer layers of solar-like stars. Upper layers of the corresponding 1D standard models were then replaced by the layers obtained from the horizontally averaged 3D models. The frequency differences between these patched models and the 1D standard models were then calculated using the adiabatic approximation and allowed us to constrain the Kjeldsen et al. power law, as well as a Lorentzian formulation. Results. We find that the surface effects on modal frequencies depend significantly on both the effective temperature and the surface gravity. We further provide the variation in the parameters related to the surface-effect corrections using their power law as well as a Lorentzian formulation. Scaling relations between these parameters and the elevation (related to the Mach number) is also provided. The Lorentzian formulation is shown to be more robust for the whole frequency spectrum, while the power law is not suitable for the frequency shifts in the frequency range above νmax. Finally, we show that, owing to turbulent pressure, the elevation of the uppermost layers modifies the location of the hydrogen ionization zone and consequently introduces glitches in the surface effects for models with high (low) effective temperature (surface gravity). Conclusions. Surface-effect corrections vary significantly across the HR diagram. Therefore, empirical relations like those by Kjeldsen et al. must not be calibrated on the Sun but should instead be constrained using realistic physical modeling as provided by 3D hydrodynamical simulations.

Abstract: We provide a complete characterization of hydrodynamic transport consistent with the second law of thermodynamics at arbitrary orders in the gradient expansion. A key ingredient in facilitating this analysis is the notion of adiabatic hydrodynamics, which enables isolation of the genuinely dissipative parts of transport. We demonstrate that most transport is adiabatic. Furthermore, in the dissipative part, only terms at the leading order in gradient expansion are constrained to be sign definite by the second law (as has been derived before).

Abstract: We work out the theory and applications of a fast quasiadiabatic approach to speed up slow adiabatic manipulations of quantum systems by driving a control parameter as near to the adiabatic limit as possible over the entire protocol duration. We find characteristic time scales, such as the minimal time to achieve fidelity 1, and the optimality of the approach within the iterative superadiabatic sequence. Specifically, we show that the population inversion in a two-level system, the splitting and cotunneling of two-interacting bosons, and the stirring of a Tonks-Girardeau gas on a ring to achieve mesoscopic superpositions of many-body rotating and nonrotating states can be significantly speeded up.

Abstract: We argue that in addition to the Hall conductance and the nondissipative component of the viscous tensor, there exists a third independent transport coefficient, which is precisely quantized. It takes constant values along quantum Hall plateaus. We show that the new coefficient is the Chern number of a vector bundle over moduli space of surfaces of genus 2 or higher and therefore cannot change continuously along the plateau. As such, it does not transpire on a sphere or a torus. In the linear response theory, this coefficient determines intensive forces exerted on electronic fluid by adiabatic deformations of geometry and represents the effect of the gravitational anomaly. We also present the method of computing the transport coefficients for quantum Hall states.

Abstract: Adiabatic state engineering is a powerful technique in quantum information and quantum control. However, its performance is limited by the adiabatic theorem of quantum mechanics. In this scenario, shortcuts to adiabaticity, such as provided by the superadiabatic theory, constitute a valuable tool to speed up the adiabatic quantum behavior. Here, we propose a superadiabatic route to implement universal quantum computation. Our method is based on the realization of piecewise controlled superadiabatic evolutions. Remarkably, they can be obtained by simple time-independent counter-diabatic Hamiltonians. In particular, we discuss the implementation of fast rotation gates and arbitrary n-qubit controlled gates, which can be used to design different sets of universal quantum gates. Concerning the energy cost of the superadiabatic implementation, we show that it is dictated by the quantum speed limit, providing an upper bound for the corresponding adiabatic counterparts.

Abstract: The renormalization of electronic eigenenergies due to electron-phonon coupling is sizable in many materials with light atoms. This effect, often neglected in ab-initio calculations, can be computed using the perturbation-based Allen-Heine-Cardona theory in the adiabatic or non-adiabatic harmonic approximation. After a short description of the numerous recent progresses in this field, and a brief overview of the theory, we focus on the issue of phonon wavevector sampling convergence, until now poorly understood. Indeed, the renormalization is obtained numerically through a q-point sampling inside the BZ. For q-points close to G, we show that a divergence due to non-zero Born effective charge appears in the electron-phonon matrix elements, leading to a divergence of the integral over the BZ for band extrema. Although it should vanish for non-polar materials, unphysical residual Born effective charges are usually present in ab-initio calculations. Here, we propose a solution that improves the coupled q-point convergence dramatically. For polar materials, the problem is more severe: the divergence of the integral does not disappear in the adiabatic harmonic approximation, but only in the non-adiabatic harmonic approximation. In all cases, we study in detail the convergence behavior of the renormalization as the q-point sampling goes to infinity and the imaginary broadening parameter goes to zero. This allows extrapolation, thus enabling a systematic way to converge the renormalization for both polar and non-polar materials. Finally, the adiabatic and non-adiabatic theory, with corrections for the divergence problem, are applied to the study of five semiconductors and insulators: a-AlN, b-AlN, BN, diamond and silicon. For these five materials, we present the zero-point renormalization, temperature dependence, phonon-induced lifetime broadening and the renormalized electronic bandstructure.

Abstract: Tunneling is often claimed to be the key mechanism underlying possible speedups in quantum optimization via quantum annealing (QA), especially for problems featuring a cost function with tall and thin barriers. We present and analyze several counterexamples from the class of perturbed Hamming-weight optimization problems with qubit permutation symmetry. We first show that, for these problems, the adiabatic dynamics that make tunneling possible should be understood not in terms of the cost function but rather the semi-classical potential arising from the spin-coherent path integral formalism. We then provide an example where the shape of the barrier in the final cost function is short and wide, which might suggest no quantum advantage for QA, yet where tunneling renders QA superior to simulated annealing in the adiabatic regime. However, the adiabatic dynamics turn out not be optimal. Instead, an evolution involving a sequence of diabatic transitions through many avoided level-crossings, involving no tunneling, is optimal and outperforms adiabatic QA. We show that this phenomenon of speedup by diabatic transitions is not unique to this example, and we provide an example where it provides an exponential speedup over adiabatic QA. In yet another twist, we show that a classical algorithm, spin vector dynamics, is at least as efficient as diabatic QA. Finally, in a different example with a convex cost function, the diabatic transitions result in a speedup relative to both adiabatic QA with tunneling and classical spin vector dynamics.

Abstract: We investigate the properties of a spinless Fermi gas close to a p-wave interaction resonance. We show that the effects of interaction near a p-wave resonance are captured by two contacts, which are related to the variation of energy with the p-wave scattering volume v and with the effective range R in two adiabatic theorems. Exact pressure and virial relations are derived. We show how the two contacts determine the leading and subleading asymptotic behavior of the momentum distribution (∼1/k^{2} and ∼1/k^{4}) and how they can be measured experimentally by radio-frequency and photoassociation spectroscopies. Finally, we evaluate the two contacts at high temperature with a virial expansion.

Abstract: We derive the effective one-dimensional Schrodinger-Pauli equation for electrons constrained to move on a space curve The electrons are confined using a double thin-wall quantization procedure with adiabatic separation of fast and slow quantum degrees of freedom This procedure is capable of yielding a correct Hermitian one-dimensional Schrodinger-Pauli operator We find that the torsion of the space curve generates an additional quantum geometric potential, adding to the well-known curvature-induced one Finally, we derive an analytic form of the one-dimensional Hamiltonian for spin-orbit coupled electrons in a nanoscale helical wire

Abstract: We investigate theoretically the quantum Rabi model in the large-detuning regime. When the frequency of the cavity field is near one-third of the atomic transition frequency, we show that there exists a resonant three-photon coupling via intermediate states connected by counter-rotating processes. We derive an effective Hamiltonian of the three-photon coupling, which determines the magnitude of the energy splitting and the position of the resonance analytically. In addition, we present a scheme of three-photon generation based on adiabatic passage across the resonance.

Abstract: We introduce a general framework for analyzing the thermodynamics of small systems that are driven by both a periodic temperature variation and some external parameter modulating their energy. This set-up covers, in particular, periodic micro and nano-heat engines. In a first step, we show how to express total entropy production by properly identified time-independent affinities and currents without making a linear response assumption. In linear response, kinetic coefficients akin to Onsager coefficients can be identified. Specializing to a Fokker-Planck type dynamics, we show that these coefficients can be expressed as a sum of an adiabatic contribution and one reminiscent of a Green-Kubo expression that contains deviations from adiabaticity. Furthermore, we show that the generalized kinetic coefficients fulfill an Onsager-Casimir type symmetry tracing back to microscopic reversibility. This symmetry allows for non-identical off-diagonal coefficients if the driving protocols are not symmetric under time-reversal. We then derive a novel constraint on the kinetic coefficients that is sharper than the second law and provides an efficiency-dependent bound on power. As one consequence, we can prove that the power vanishes at least linearly when approaching Carnot efficiency. We illustrate our general framework by explicitly working out the paradigmatic case of a Brownian heat engine realized by a colloidal particle in a time-dependent harmonic trap subject to a periodic temperature profile. This case study reveals inter alia that our new general bound on power is asymptotically tight.

Abstract: Astrophysical shocks are often collisionless shocks, in which the changes in plasma flow and temperatures across the shock are established not through Coulomb interactions, but through electric and magnetic fields. An open question about collisionless shocks is whether electrons and ions each establish their own post-shock temperature (non-equilibration of temperatures), or whether they quickly equilibrate in the shock region. Here we provide a simple, thermodynamic, relation for the minimum electron-ion temperature ratios that should be expected as a function of Mach number. The basic assumption is that the enthalpy-flux of the electrons is conserved separately, but that all particle species should undergo the same density jump across the shock, in order for the plasma to remain charge neutral. The only form of additional electron heating that we allow for is adiabatic heating, caused by the compression of the electron gas. These assumptions result in an analytic treatment of expected electron-ion temperature ratio that agrees with observations of collisionless shocks: at low sonic Mach numbers, Ms . 2, the electron-ion temperature ratio is close to unity, whereas for Mach numbers above Ms 60 the electron-ion temperature ratio asymptotically approaches a temperature ratio of Te=Ti = me=hmii. In the intermediate Mach number range the electron-ion temperature ratio scales as Te=Ti/ M 2 s . In addition, we calculate the electron-ion temperature ratios under the assumption of adiabatic heating of the electrons only, which results in a higher electronion temperature ratio, but preserves the Te=Ti/ M 2 s scaling. We also show that for magnetised shocks the electron-ion temperature ratio approaches the asymptotic value Te=Ti = me=hmii for lower magnetosonic Mach numbers (Mms), mainly because for a strongly magnetised shock the sonic Mach number is larger than the magnetosonic Mach number (Mms Ms). The predicted scaling of the electron-ion temperature ratio is in agreement with observational data for magnetosonic Mach numbers between 2 and 10, but for supernova remnants the relation requires that the inferred Mach numbers for the observations are overestimated, perhaps as a result of upstream heating in the cosmic-ray precursor. In addition to predicting a minimal electron-ion temperature ratio, we also heuristically incorporate ion-electron heat exchange at the shock, quantified with a dimensionless parameter , which is the fraction of the enthalpy-flux di erence between electrons and ions that is used for equilibrating the electron and ion temperatures. Comparing the model to existing observations in the solar system and supernova remnants suggests that the data are best described by & 5%, but also provides a hint that the Mach number of some supernova remnant shocks may have been overestimated; perhaps as a result of heating in the cosmic-ray precursor.

Abstract: Adiabatic superconductor logic (ASL), including adiabatic quantum-flux-parametron (AQFP) logic, exhibits high energy efficiency because its bit energy can be decreased below the thermal energy through adiabatic switching operations. In the present paper, we present the general scaling laws of ASL and compare the energy efficiency of ASL with those of other energy-efficient logics. Also, we discuss the minimum energy-delay product (EDP) of ASL at finite temperature. Our study shows that there is a maximum temperature at which the EDP can reach the quantum limit given by ħ/2, which is dependent on the superconductor material and the Josephson junction quality, and that it is reasonable to operate ASL at cryogenic temperatures in order to achieve an EDP that approaches ħ/2.

Abstract: In the present series of papers we propose a consistent description of the mass loss process. To study the effects of intrinsic magnetic field of a close-orbit giant exoplanet (so-called Hot Jupiter) on the atmospheric material escape and formation of planetary inner magnetosphere in a comprehensive way, we start with a hydrodynamic model of an upper atmosphere expansion presented in this paper. While considering a simple hydrogen atmosphere model, we focus on selfconsistent inclusion of the effects of radiative heating and ionization of the atmospheric gas with its consequent expansion in the outer space. Primary attention is paid to investigation of the role of specific conditions at the inner and outer boundaries of the simulation domain, under which different regimes of material escape (free- and restricted- flow) are formed. Comparative study of different processes, such as XUV heating, material ionization and recombination, H3+ cooling, adiabatic and Lyman-alpha cooling, Lyman-alpha reabsorption is performed. We confirm basic consistence of the outcomes of our modeling with the results of other hydrodynamic models of expanding planetary atmospheres. In particular, we obtain that under the typical conditions of an orbital distance 0.05 AU around a Sun-type star a Hot Jupiter plasma envelope may reach maximum temperatures up to ~9000K with a hydrodynamic escape speed ~9 km/s resulting in the mass loss rates ~(4-7)*10^10 g*s . In the range of considered stellar-planetary parameters and XUV fluxes that is close to mass loss in the energy limited case. The inclusion of planetary intrinsic magnetic fields in the model is a subject of the following up paper (Paper II).

Abstract: We investigate universal relations in a spinless Fermi gas near a p-wave Feshbach resonance, and show that the momentum distribution n_{k} has an asymptote proportional to k^{-2} with the proportionality constant-the p-wave contact-scaling with the number of closed-channel molecules. We prove the adiabatic sweep theorem for a p-wave resonance which reveals the thermodynamic implication of the p-wave contact. In contrast to the unitary Fermi gas in which Tan's contact is universal, the p-wave contact depends on the short-range details of the interaction.