Journal Article10.1002/ANIE.200903895
Two-dimensional triangular and square heterometallic clusters: influence of the closed-shell d10 electronic configuration.
Sabrina Sculfort,Pierre Croizat,Abdelatif Messaoudi,Marc Bénard,Marie-Madeleine Rohmer,Richard Welter,Pierre Braunstein +6 more
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About: This article is published in Angewandte Chemie. The article was published on 14 Dec 2009. The article focuses on the topics: Open shell & Square (algebra).
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Citations
Intramolecular d10–d10 interactions in heterometallic clusters of the transition metals
TL;DR: A critical review of the synthesis and structures of heterometallic clusters of the transition metals in which intra- rather than intermolecular d(10)-d(10) interactions are at work, in order to limit the role of packing effects.
Complementary Operando Spectroscopy identification of in-situ generated metastable charge-asymmetry Cu2-CuN3 clusters for CO2 reduction to ethanol
Xiaozhi Su,Zhuoli Jiang,Jing Zhou,Hengjie Liu,Danni Zhou,Huishan Shang,Xingming Ni,Zheng Peng,Fan Yang,Wenxing Chen,Zeming Qi,Dingsheng Wang,Yu Wang +12 more
TL;DR: In this article , a CO2RR catalyst comprising of CuO clusters supported on N-doped carbon nanosheets, which exhibited high C2+ products Faradaic efficiency of 73% including decent ethanol selectivity of 51% with a partial current density of 14.4 mA/cm-2 at -1.1 V vs. RHE.
184
Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands.
TL;DR: The aim of this review is to highlight how the diversity generated by N-substitution in the well-known short-bite ligand bis(diphenylphosphino)amine (DPPA) allows a fine-tuning of the ligand properties and offers a considerable scope for tailoring the properties and applications of their corresponding metal complexes.
101
Tetrahedral Gold(I) Clusters with Carba-closo-dodecaboranylethynido Ligands: [{12-(R3PAu)2CC-closo-1-CB11H11}2]†
TL;DR: Distorted tetrahedral Au4 clusters with carboranylethynido ligands are reported, formed by selfassembly of two dinuclear gold(I) complexes and they are present in the solid sate and for the first time in solution, as well.
81
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Covalent radii revisited
Beatriz Cordero,Verónica Gómez,Ana E. Platero-Prats,Marc Revés,Jorge Echeverría,Eduard Cremades,Flavia Barragán,Santiago Alvarez +7 more
TL;DR: A new set of covalent atomic radii has been deduced from crystallographic data for most of the elements with atomic numbers up to 96 and shows a well behaved periodic dependence that allows us to interpolate a few radii for elements for which structural data is lacking.
A set of f-polarization functions for pseudo-potential basis sets of the transition metals ScCu, YAg and LaAu
A.W. Ehlers,Marlis Böhme,Stefan Dapprich,A. Gobbi,A. Höllwarth,Volker Jonas,K.F. Köhler,R. Stegmann,A. Veldkamp,Gernot Frenking +9 more
TL;DR: In this paper, a set of seven-component f-type polarization functions has been optimized for use with the pseudo-potentials of Hay and Wadt at the CISD level of theory for the transition metals ScCu, YAg, LaAu in the energetically lowest-lying s 1 d n electronic state.
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Theoretical chemistry of gold.
TL;DR: The theoretical interpretation of the aurophilic attraction is discussed in detail and a large body of appropriate calculations now exist and their main conclusions are summarized.
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