The impact of nanoscience on heterogeneous catalysis
TL;DR: Advances in characterization methods have led to a molecular-level understanding of the relationships between nanoparticle properties and catalytic performance, and this knowledge is contributing to the design and development of new catalysts.
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Abstract: Most catalysts consist of nanometer-sized particles dispersed on a high-surface-area support. Advances in characterization methods have led to a molecular-level understanding of the relationships between nanoparticle properties and catalytic performance. Together with novel approaches to nanoparticle synthesis, this knowledge is contributing to the design and development of new catalysts.
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TL;DR: Results suggest that supported clusters, in general, may have unusual catalytic properties as one dimension of the cluster becomes smaller than three atomic spacings.
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TL;DR: The Structure of Solid Surfaces and Adsorbate Overlayers as discussed by the authors, the Binding of Molecules to Surfaces, and the Kinetics of Adsorption are discussed.
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Krijn P. de Jong,John W. Geus +1 more
TL;DR: A review on the growth of nanofibers using metallic particles as a catalyst to precipitate the graphitic carbon can be found in this paper, where the authors summarize some of the earlier literature that has contributed greatly to understand the nucleation and growth of carbon carbon and nanotubes and describe in detail recent progress to control the fiber surface structure, texture, and growth into mechanically strong agglomerates.
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Flemming Besenbacher,Ib Chorkendorff,Clausen Bjerne Steffen,Bjørk Hammer,A.M. Molenbroek,Jens K. Nørskov,Ivan Stensgaard +6 more
TL;DR: Insight into the structure of surface alloys combined with an understanding of the relation between the surface composition and reactivity is shown to lead directly to new ideas for catalyst design.
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Oxidative dyhydrogenation of short chain alkanes on supported vanadium oxide catalysts
T. Blasco,J.M. López Nieto +1 more
TL;DR: In this article, the main data appeared in the last years on the oxidative dehydrogenation (ODH) of short chain alkanes on supported vanadium oxide catalysts, and it was concluded that tetrahedral V5+-species are active and selective sites in the ODH of C2-C4 alkanes.
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