Journal Article10.1016/0022-2852(82)90134-5
The E-B band system of diatomic iodine
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TL;DR: In this article, the EO g + ion-pair state correlates diabatically with the ground state I − ( 1 S 0 ) + I + ( 3 P 2 ) of the separated ions.
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About: This article is published in Journal of Molecular Spectroscopy. The article was published on 01 Oct 1982. The article focuses on the topics: Ground state.
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Citations
Femtosecond wave packet and chemical reaction dynamics of iodine in solution: Tunable probe study of motion along the reaction coordinate
TL;DR: In this article, one-and two-color time-domain probing of the resonant dichroic response of iodine in n−hexane following femtosecond B•X excitation at 580 nm is described.
179
Multiphoton Spectra and States of Halogens
J. C. D. Brand,A. R. Hoy +1 more
TL;DR: In this paper, the Franck-Condon effect was used to prevent the simultaneous excitation of two o r three photons using the conveniently placed, low-lying excited sQtes in the visible region for the initial step, in effect broadening the perspective from the ground state to include that from lower ex...
121
The Franck—Condon Principle in Bound‐Free Transitions
TL;DR: In this article, the role of Franck-Condon in the interpretation and analysis of transitions lie-libre de molecules diatomiques, dans la cadre classique, semi-classique ou quantique, is discussed.
111
Solvation Ultrafast Dynamics of Reactions. 11. Dissociation and Caging Dynamics in the Gas-to-Liquid Transition Region
Christoph Lienau,Ahmed H. Zewail +1 more
TL;DR: Lienau et al. as discussed by the authors presented a microscopic picture of the elementary processes under the free and solvation conditions encompassing the different density regimes in the gas-to-liquid transition region.
83
Einstein A-coefficients and transition dipole moments for some ion-pair to valence transitions in I2
Kenneth P. Lawley,Philip J. Jewsbury,Trevor Ridley,Patrick R. R. Langridge-Smith,Robert J. Donovan +4 more
TL;DR: The relative fluorescence intensities of all the strong electronic transitions from five of the first cluster of ion-pair (IP) states of I2 and from three states in the second cluster have been measured as discussed by the authors.
64
References
Atomic polarizabilities and shielding factors
TL;DR: In this article, a detailed discussion of the methods of calculating atomic polarizabilities and shielding factors and the relationships between them are demonstrated, and a more accurate procedure, the coupled Hartree-Fock approximation, is described.
854
Perturbation theory and ionic models for alkali halide systems. I Diatomics
Paul Brumer,Martin Karplus +1 more
TL;DR: In this article, the exchange perturbation theory is used to analyze the interaction energy and dipole moment of alkali halide diatomics and it is shown that extensions of the models to include distortion effects can be formulated and these give rise to effective polarizabilities of the ions in the diatomic.
296
Molecular constants and Dunham expansion parameters describing the B-X system of the iodine molecule
TL;DR: In this paper, new molecular constants and polynomial expansion parameters for the B - X system of iodine were given for the bands with 0 ≤ v " ≤ 9 and 1 ≤ v '' ≤ 62", with standard deviations of 0.001, 0.0017, and 0.004 cm −1, respectively.
189
Two-step polarization-labeling spectroscopy of excited states of Na 2
TL;DR: Two-step polarization-labeling spectroscopy of diatomic molecules is described in this paper, where formulas for relative transition intensities are derived, and their use in determining angular momenta of molecular states is discussed.
133
Reinterpretation of the emission spectrum of I2 in argon
TL;DR: In this paper, the emission spectrum of I2 in Ar is examined as a function of pressure and temperature, and evidence is found for at least twelve of the ion-pair states, of which D'(Zg) is the lowest.
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