Journal Article10.1039/B009240L
Syntheses and X-ray crystal structures of tris(imido)arsenate anions
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TL;DR: In this article, a tris(imido)arsenate anions are produced by the reaction of 3 equivalents of RNH2 with AsCl3 in thf-NEt3 followed by metallation with three equivalents of BunLi.
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Abstract: Lithium salts of tris(imido)arsenate anions are produced by the reaction of 3 equivalents of RNH2 with AsCl3 in thf–NEt3 followed by metallation with 3 equivalents of BunLi. These complexes form ion-contacted dimers in the solid-state whereby two As(NR)33− trianions sandwich six lithium cations in irregular 14 membered core configurations whose degrees of distortion are dictated by the differing ways in which the lithium cations are solvated.
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From neutral iminophosphoranes to multianionic phosphazenates. The coordination chemistry of imino–aza-P(V) ligands
TL;DR: In this paper, the chemistry and coordination behavior of imino-aza phosphorus(V) ligands focussing on s- and p-block as well as Group 11 and 12 metal complexes are discussed.
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TL;DR: Experimental evidence that S-N bonding is predominantly governed by electrostatic interaction rather than by valence expansion employing d-orbitals is taken.
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Bis(2-pyridyl) and Tris(2-pyridyl) Compounds of Gallium and Indium via a Redox-Transmetalation Route.
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References
Crystal handling at low temperatures
Thomas Kottke,Dietmar Stalke +1 more
TL;DR: In this paper, the cooling of a crystal in combination with the use of a protecting oil facilitates the handling and transfer to a diffractometer of even very sensitive material, and the method is explained and the required device is described in this work.
1.1K
Synthetic applications of p block metal dimethylamido reagents
TL;DR: In this paper, a review describes the synthetic applications of p block metal dimethylamido reagents to a range of p-block metal compounds and the structures and reactivities of the imido and phosphinidene complexes produced.
95
Low-temperature synthesis of zintl compounds with a single-source molecular precursor
Michael A. Beswick,Nick Choi,Christopher N. Harmer,Alexander D. Hopkins,Mary McPartlin,Dominic S. Wright +5 more
TL;DR: The heterobimetallic phosphinidene complex constitutes a stable molecular single-source precursor to Zintl compounds and provides a potential low-temperature route to photoactive alkali metal antimonates.
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