Journal Article10.1021/AC60323A005
Semiintegral electroanalysis. Analog implementation
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About: This article is published in Analytical Chemistry. The article was published on 01 Jan 1973.
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Citations
Cyclic Voltammetry—“Electrochemical Spectroscopy”. New Analytical Methods (25)
TL;DR: The cyclic voltammetry has the further attraction of providing information not only on the thermodynamics of redox processes but also on the kinetics of heterogeneous electron-transfer reactions and coupled chemical reactions as discussed by the authors.
574
Realization of a Constant Phase Element and Its Performance Study in a Differentiator Circuit
TL;DR: A fractional-order differentiator circuit has been constructed using the CPE, and its performance has been compared with the simulated results.
262
Initialization, conceptualization, and application in the generalized (fractional) calculus.
Carl F. Lorenzo,Tom T. Hartley +1 more
TL;DR: A modified set of definitions for the fractional calculus is provided which formally include the effects of initialization, and a new generalized form for the Laplace transform of the generalized differintegral is derived.
Fractional diffusion equation on fractals: one-dimensional case and asymptotic behaviour
M Giona,H. E. Roman +1 more
TL;DR: In this article, a fractional differential equation is studied and its application for describing diffusion on random fractal structures is considered, which represents the simplest generalization of the fractional diffusion equation valid in Euclidean systems.
143
References
The replacement of Fick's laws by a formulation involving semidifferentiation
Keith B. Oldham,Jerome Spanier +1 more
TL;DR: In this article, the authors proposed an improved starting point for the prediction of voltammetric relationships, compared with the classical Fick's law approach, in that only one additional condition (representing the electrical signal applied to the cell) is needed to characterize the experiment.
193
The analog method for solution of problems involving diffusion to the electrode: I. Diffusion to a sphere with langmuirian adsorption solved by analog method
Karel Holub,L. Němec +1 more
TL;DR: In this paper, the RC network is used as a new functional element for analog computation with transfer function s 1 2 2, which makes it possible to obtain analog solutions of many diffusion problems in electrochemistry.
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