Self-associated, "distillable" ionic media.
TL;DR: Liquid or low melting association products of carbon dioxide and a secondary amine, both neutral molecules that may be gaseous, are recognised as "distillable" ionic media.
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Abstract: Liquid or low melting association products of carbon dioxide and a secondary amine, both neutral molecules that may be gaseous, are recognised as "distillable" ionic media.
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Citations
The distillation and volatility of ionic liquids
Martyn J. Earle,José M. S. S. Esperança,Manuela A. Gilea,José N. Canongia Lopes,Luís Paulo N. Rebelo,Joseph W. Magee,Kenneth R. Seddon,Jason A. Widegren +7 more
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References
Ionic Liquids-New "Solutions" for Transition Metal Catalysis.
Peter Wasserscheid,Wilhelm Keim +1 more
TL;DR: There are indications that switching from a normal organic solvent to an ionic liquid can lead to novel and unusual chemical reactivity, which opens up a wide field for future investigations into this new class of solvents in catalytic applications.
5.7K
CO2 Capture by a Task-Specific Ionic Liquid
TL;DR: A new room temperature ionic liquid incorporating a cation with an appended amine group is produced, comparable in efficiency for CO2 capture to commercial amine sequestering reagents, and yet is nonvolatile and does not require water to function.
2.2K
A short history of ionic liquids—from molten salts to neoteric solvents
TL;DR: Ionic liquids, defined here as salts with melting temperatures below 100 °C, evolved from traditional high temperature molten salts and were observed as far back as the mid 19th century.
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Organic Chemical Reactions in Supercritical Water.
TL;DR: The paper discusses the use of supercritical water in the following reactions: hydrogenation/dehydrogenation; C-C bond formation; rearrangements; hydration/ dehydration; elimination; hydrolysis; partial oxidation; H-D exchange; decomposition; and oxidation.
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