Journal Article10.1351/PAC199365112313
Replication and assembly
Cecilia Andreu,René Beerli,Neil R. Branda,M. Morgan Conn,J. De Mendoza,Amalia Galán,Ivan Huc,Yoko Kato,M. Tymoschenko,C. Valdez,Edward A. Wintner,Wyler Rene,Julius Rebek +12 more
TL;DR: Molecules bearing surfaces capable of recognition phenomena can be covalently attached to each other to give self-complementary structures that are particularly desirable targets for synthetic and nucleation studies.
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Abstract: Molecules bearing surfaces capable of recognition phenomena can be covalently attached to each other to give self-complementary structures. Such molecules can reveal autocatalytic effects as replicators, and they are able to assemble in a variety of superstructures. Closed-shell assemblies, capable of inclusion phenomena are particularly desirable targets for synthetic and nucleation studies.
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Control of peptide conformation by the Thorpe-Ingold effect (C alpha-tetrasubstitution).
TL;DR: The preferred conformations of peptides heavily based on the currently extensively exploited achiral and chiral α-amino acids with a quaternary α-carbon atom, as determined by conformational energy computations, crystal-state (x-ray diffraction) analyses, and solution (1H-NMR and spectroscopic) investigations, are reviewed in this paper.
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Molecular recognition of organic acids and anions — Receptor models for carboxylates, amino acids, and nucleotides
TL;DR: For a long time, far less interest has been focussed on the complexation of anions even if the primal strategies were comparable, and only in recent years have the advances made been increasingly dynamic.
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Synthesis of α,α-dialkylated amino acids with adenine or thymine residues a new mild and facile hydrolysis of hydantoins
TL;DR: The synthesis of α,α-dialkylated amino acids which contain two adenine or thymine residues in their side chains is presented and a mild method for the cleavage of hydantoins is introduced.
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