Reduction of Nitro Compounds Using 3d-Non-Noble Metal Catalysts
TL;DR: This review will comprehensively discuss the use of homogeneous and heterogeneous catalysts based on non-noble 3d-metals for the reduction of nitro compounds using various reductants.
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Abstract: The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led to their tremendous achievements over the last years prompting their greater application as “standard” catalysts. In this review, we will comprehensively discuss the use of homogeneous and heterogeneous catalysts based on non-noble 3d-metals for the reduction of nitro compounds using various reductants. The different systems will be revised considering both the catalytic performances and synthetic aspects highlighting also their advantages and disadvantages.
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Hydrogen Processing by FeIII‐Exchanged Montmorillonite: A Unique Geochemical Protocol
Boyapati M. Choudary,Mannepalli Lakshmi Kantam,Kalluri V. S. Ranganath,Kottapalli Koteswara Rao +3 more
TL;DR: The production of hydrogen by the relay of electrons from I − to H + in an acidic, aqueous medium and the consumption of Hydrogen by reductive N acylation open up enormous opportunities in hydrogen chemistry.
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Rod-Like Co2P Nanostructures: Improved Synthesis, Catalytic Property and Application in the Removal of Heavy Metal
TL;DR: In this paper, rod-like cobalt phosphide (Co2P) nanostructures were successfully synthesized at a large scale via an improved water-ethanol mixed-solvothermal route.
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Cobalt Complexes Catalyze Reduction of Nitro Compounds: Mechanistic Studies
Sushil Kumar,Rajeev Gupta +1 more
- 21 Sep 2017
TL;DR: Mononuclear Co2+/3+ complexes of 13-membered amide-based macrocycles have been synthesized, characterized and utilized in the chemo-selective reduction of assorted nitro compounds including aromatic, heterocyclic and aliphatic ones as mentioned in this paper.
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TL;DR: In this article, the authors present the synshesis of cis and trans 4-AMINOCYCLOHEXYL-D-ALANINE DERIVATIVES and DETERMINATION of their sterochEMISTRY.
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Synthesis, structure and catalytic activity of the supported Ni catalysts for highly efficient one-step hydrogenation of 1,5-dinitronaphthalene to 1,5-diaminodecahydronaphthalene
TL;DR: In this paper, a series of supported nickel catalysts have been synthesized through impregnation, characterized by X-ray diffraction, N 2 sorption measurement, temperature programmed H 2 reduction and Xray photoelectron spectroscopy.
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