Journal Article10.1021/OM970103Z
(Phenylboratabenzene)zirconium Complexes: Tuning the Reactivity of an Olefin Polymerization Catalyst
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TL;DR: The reaction of 2 equiv of lithium 1-phenylboratabenzene with ZrCl4 in ether with C2H4 was studied in a single-crystal X-ray diffraction study as mentioned in this paper.
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About: This article is published in Organometallics. The article was published on 10 Jun 1997. The article focuses on the topics: Methylaluminoxane & Zirconium.
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Citations
Organo transition metal initiated living polymerizations
TL;DR: The recent advances of organo-transition metal initiated polymerizations and copolymerizations of polar and nonpolar monomers are described in this article, where the authors deal with Group 3-6 and Group 8-10 metal-initiated polymerizations.
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The chemistry of borabenzenes (1986–2000)
TL;DR: The history of the chemistry of borabenzenes from 1986 to 2000 is described in this paper, where a number of important advances were made in understanding the structure, bonding, and reactivity of BORABENzenes.
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Group 4 metal complexes for homogeneous olefin polymerisation: a short tutorial review
TL;DR: A short tutorial review gives an overview of homogenous transition metal Ziegler-Natta catalysis in general as well as an overview for a selection of Group 4 post-metallocene catalysts as mentioned in this paper.
113
(Boratabenzene)(cyclooctatetraenyl) lanthanide complexes: a new type of organometallic single-ion magnet
TL;DR: A series of new sandwich type lanthanide complexes containing both boratabenzene and cyclooctatetraenyl ligands, (C5H5BR)Ln(COT), were synthesized in this article.
References
Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
TL;DR: In contrast to heterogeneous Ziegler-Natta catalysts, homogeneous metallocene-based catalysts as discussed by the authors allow efficient control of regio-and stereoregularities, molecular weights and molecular weight distributions, and comonomer incorporation.
Organocobalt Compounds in the Synthesis of Pyridines–An Example of Structure‐Effectivity Relationships in Homogeneous Catalýsis
TL;DR: In this article, it was shown that the organo group Y remains attached to the cobalt throughout the catalytic cycle, which opened up the possibility of optimizing the catalyst by varying the controlling ligand Y.
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Effects of regiochemical and stereochemical errors on the course of isotactic propene polyinsertion promoted by homogeneous Ziegler-Natta catalysts
TL;DR: In this paper, the effects of regiochemical and stereochemical errors on the kinetic course of isotactic propene polyinsertion promoted by two typical homogeneous metallocene catalysts are analyzed in detail.
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Metallocene Catalysts Initiate New Era In Polymer Synthesis
TL;DR: Metallocene catalysts are "just a rumble on the tracks," says one industry consultant, "but it's certainly a train that's coming." The plastics industry, by most accounts, is moving into an era based on a new generation of catalysts and entirely new polymeric materials as discussed by the authors.
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