Open AccessBook
Petroleum Refining: Technology and Economics
James H. Gary,Glenn Handwerk +1 more
- 01 Jan 1993
886
TL;DR: In this article, Yarsintez et al. presented an economic model for delayed Coking operation and delay Coking process, and showed that delay can increase the costs of Coking and Coking operations.
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Abstract: Introduction Refinery Processes and Operations Historic Overview Product Demand and Supply U.S. Statistics World Statistics Industry Characteristics Refinery Economics Cost Estimation Refinery Complexity Refinery Flow Scheme and Chapter Outline Refinery Products Low-Boiling Products Gasoline Gasoline Specifications Distillate Fuels Residual Fuel Oils Refinery Feedstocks Crude Oil Properties Composition of Petroleum Crudes Suitable for Asphalt Manufacture Crude Distillation Desalting Crude Oils Atmospheric Topping Unit Vacuum Distillation Auxiliary Equipment Crude Distillation Unit Products Case-Study Problem: Crude Units Coking and Thermal Processes Types, Properties, and Uses of Petroleum Coke Process Description-Delayed Coking Operation-Delayed Coking Process Description-Flexicoking Process Description-Fluid Coking Yields from Flexicoking and Fluid Coking Capital Costs and Utilities for Flexicoking and Fluid Coking Visbreaking Case-Study Problem: Delayed Coker Catalytic Cracking Fluidized Bed Catalytic Cracking New Designs for Fluidized Bed Catalytic Cracking Units Cracking Reactions Cracking of Paraffins Olefin Cracking Cracking of Naphthenic Hydrocarbons Aromatic Hydrocarbon Cracking Cracking Catalysts FCC Feed Pretreating Process Variables Heat Recovery Yield Estimation Capital and Operating Costs Case-Study Problem: Catalytic Cracker Catalytic Hydrocracking Hydrocracking Reactions Feed Preparation The Hydrocracking Process Hydrocracking Catalyst Process Variables Hydrocracking Yields Investment and Operating Costs Modes of Hydrocracker Operation Case-Study Problem: Hydrocracker Hydroprocessing and Resid Processing Composition of Vacuum Tower Bottoms Processing Options Hydroprocessing Expanded-Bed Hydrocracking Processes Moving-Bed Hydroprocessors Solvent Extraction Summary of Resid Processing Operations Hydrotreating Hydrotreating Catalysts Aromatics Reduction Reactions Process Variables Construction and Operating Costs Case-Study Problem: Hydrotreaters Catalytic Reforming and Isomerization Reactions Feed Preparation Catalytic Reforming Processes Reforming Catalyst Reactor Design Yields and Costs Isomerization Capital and Operating Costs Isomerization Yields Case-Study Problem: Naphtha Hydrotreater, Catalytic Reformer, and Isomerization Unit Alkylation and Polymerization Alkylation Reactions Process Variables Alkylation Feedstocks Alkylation Products Catalysts Hydrofluoric Acid Processes Sulfuric Acid Alkylation Processes Comparison of Processes Alkylation Yields and Costs Safety Issues Polymerization Case-Study Problem: Alkylation and Polymerization Product Blending Reid Vapor Pressure Octane Blending Blending for Other Properties Case-Study Problem: Gasoline Blending Octane Calculations for Pool Gasoline Case-Study Problem: Diesel and Jet Fuel Blending Supporting Processes Hydrogen Production and Purification Gas Processing Unit Acid Gas Removal Sulfur Recovery Processes Ecological Considerations in Petroleum Refining Wastewater Treatment Control of Atmospheric Pollution Noise Level Control Case-Study Problem: Saturated Gas Recovery, Amine, and Sulfur Recovery Units Refinery Economics and Planning Linear Programming Overview Refinery Linear Programming Models Economics and Planning Applications Lubricating Oil Blending Stocks Lube Oil Processing Propane Deasphalting Viscosity Index Improvement and Solvent Extraction Viscosity Index Improvement and Hydrocracking Dewaxing Hydrofinishing Finishing by Clay Contacting Environmental Impacts Petrochemical Feedstocks Aromatics Production Unsaturate Production Saturated Paraffins Additives Production from Refinery Feedstocks Use of Alcohols and Ethers Ether Production Reactions Ether Production Processes Yields Costs for Ether Production Production of Isobutylene Commercial Dehydrogenation Processes Houdry's CATOFIN ConocoPhillips Petroleum's Star UOP LLC OLEFLEX Snamprogetti Yarsintez Process Costs to Produce Isobutylene from Isobutane International Union of Pure and Applied Chemists Nomenclature Isooctene and Isooctane Production Cost Estimation Rule-of-Thumb Estimates Cost-Curve Estimates Major Equipment Factor Estimates Definitive Estimates Summary Form for Cost Estimates Storage Facilities Land and Storage Requirements Steam Systems Cooling Water Systems Other Utility Systems Application of Cost Estimation Techniques Economic Evaluation Definitions Return on Original Investment Payout Time Discounted Cash Flow Rate of Return Case-Study Problem: Economic Evaluation Case-Study Problem: Economic Solution Appendix A: Definitions of Refining Terms Appendix B: Physical Properties Appendix C: U.S. Bureau of Mines Routine Analyses of Selected Crude Oils Appendix D: Economic Evaluation Example Problem Appendix E: Photographs Index *Most chapters include Problems, Notes, and Additional Reading sections
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Lowering Saudi Arabia’s fuel consumption and energy system costs without increasing end consumer prices
TL;DR: In this article, an approach that could help the country to reduce substantively its current fuel consumption and could result in a net economic gain without increasing current end consumer prices and while maintaining positive utility sector net cash flows is presented.
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Energy efficiency improvement and cost saving opportunities forpetroleum refineries
Ernst Worrell,Christina Galitsky +1 more
- 15 Feb 2005
TL;DR: In this article, the authors provide information on potential energy efficiency opportunities for petroleum refineries and their work with the U.S. Environmental Protection Agency's ENERGY STAR (R) program.
Microwave-assisted ultraviolet digestion of petroleum coke for the simultaneous determination of nickel, vanadium and sulfur by ICP-OES.
Jussiane S.S. Oliveira,Rochele S. Picoloto,Cezar A. Bizzi,Paola A. Mello,Juliano Smanioto Barin,Erico M.M. Flores +5 more
TL;DR: A method for the simultaneous determination of Ni, V and S in petroleum coke by inductively coupled plasma optical emission spectrometry (ICP-OES) after microwave-assisted ultraviolet digestion (MW-UV) in closed vessels was proposed, avoiding the use of concentrated nitric acid and providing digests suitable for routine analysis by ICP- OES.
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Summer and winter nonmethane hydrocarbon emissions from on-road motor vehicles in the Midwestern United States.
TL;DR: Comparison of ambient data for the Milwaukee area with tunnel emissions showed the impact of seasonal differences in fuels and emissions on the urban atmosphere, and results of the mass balance model indicate that partially combusted components of gasoline are a major contributor to emissions of aromatic compounds and air toxic compounds.
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Dicyanamide-based ionic liquids in the liquid–liquid extraction of aromatics from alkanes: Experimental evaluation and computational predictions
Marcos Larriba,Marcos Larriba,Pablo Navarro,Maria Gonzalez-Miquel,Salama Omar,Jose Palomar,Julián García,Francisco Rodríguez +7 more
TL;DR: In this paper, the potential use of ionic liquids (ILs) in the extraction of aromatic hydrocarbons from alkanes has been studied, and the Conductor-like Screening Model for Real Solvents (COSMO-RS) methodology has been employed to predict the liquid-liquid and vapor-liquid equilibria between the ILs and solutes and solvent, and also a thermophysical characterization of the solvent.
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