Journal Article10.1021/OM201217R
Pd2(dba)3 as a Precursor of Soluble Metal Complexes and Nanoparticles: Determination of Palladium Active Species for Catalysis and Synthesis
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TL;DR: In this paper, the authors developed a convenient NMR procedure to reveal the nature of Tris(dibenzylideneacetone)dipalladium (Pd2(dba)3) and to determine the purity of the complex.
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About: This article is published in Organometallics. The article was published on 06 Mar 2012. The article focuses on the topics: Dibenzylideneacetone.
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Citations
Highly stretchable polymer semiconductor films through the nanoconfinement effect
Jie Xu,Sihong Wang,Ging-Ji Nathan Wang,Chenxin Zhu,Shaochuan Luo,Lihua Jin,Xiaodan Gu,Xiaodan Gu,Shucheng Chen,Vivian R. Feig,John W. F. To,Simon Rondeau-Gagné,Joonsuk Park,Bob C. Schroeder,Chien Lu,Jin Young Oh,Yanming Wang,Yun-Hi Kim,He Henry Yan,Robert Sinclair,Dongshan Zhou,Gi Xue,Boris Murmann,Christian Linder,Wei Cai,Jeffrey B.-H. Tok,Jong Won Chung,Jong Won Chung,Zhenan Bao +28 more
TL;DR: The increased polymer chain dynamics under nanoconfinement significantly reduces the modulus of the conjugated polymer and largely delays the onset of crack formation under strain, and the fabricated semiconducting film can be stretched up to 100% strain without affecting mobility, retaining values comparable to that of amorphous silicon.
Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions
TL;DR: It was found that replacing the chloride in the previous version of the precatalyst with a mesylate leads to a new class of precatalysts with improved solution stability and that are readily prepared from a wider range of phosphine ligands.
609
Key Green Chemistry research areas from a pharmaceutical manufacturers’ perspective revisited
Marian C. Bryan,Peter J. Dunn,David Entwistle,Fabrice Gallou,Stefan G. Koenig,John D. Hayler,Matthew R. Hickey,Shaun Hughes,Michael E. Kopach,Gerard Moine,Paul G. Richardson,Frank Roschangar,Alan Steven,Franz J. Weiberth +13 more
TL;DR: In 2007, the members of the ACS Green Chemistry Institute® Pharmaceutical Roundtable assembled a list of key green chemistry research areas to both identify transformations that would benefit from improvements in process greenness and to encourage academic research to this end as mentioned in this paper.
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Why Does Industry Not Use Immobilized Transition Metal Complexes as Catalysts
TL;DR: A review of the use of immobilized homogeneous catalysts from the point of view of process development for the pharmaceutical and fine chemical industry can be found in this article, where three different areas are discussed.
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