Palladium(II) acetate
2
TL;DR: In this article, the authors proposed a method for the dimerization of β-substituted α-olefins and β-enones, and showed that β-nodes can be decoupled from α-mixtures.
read more
Abstract: This article has no abstract.
Keywords:
oxidative dimerization of β-substituted α-olefins;
benzylic oxidation of toluenes;
π-allylpalladium complexes;
cyclopropanation;
substitution of vinylic hydrogens;
oxidation of ethylene;
cyclopropanation;
examples;
ArI Ar–Ar;
acetoxylation of arenes;
arylation of allylic alcohols with aryl halides;
α,β-enones;
1,4-dienes;
(E)- and (Z)-alkenes;
arylation of allylic alcohols;
arylation of olefins;
terminal 1,3-dienes;
2,2,7,7,12,13,17,18-octamethylisobacteriochlorin;
α,β-enones;
benzohydrofuranes;
transannular reactions of grayanotoxin-II;
cyclopentenes;
3-methyl-2-cyclopentenones;
polycyclic indoles;
β-lactams;
intramolecular cyclization via π-allylpalladium complexes;
β-aryl-α,β-unsaturated carbonyl compounds;
arenecarboxylic acids;
2,2′-bipyrroles;
bridged and spirocyclic bicycloalkenones;
ketones from halohydrins;
arylation of quinones;
cyclopropanation;
1,4-diacetoxylation of1,3-dienes;
1,4-acetoxytrifluoroacetoxylation of 1,3-dienes;
vinylation of alkyl or aryl halides;
β-aryl aldehydes;
hydrogenolysis of allylic acetates;
enones;
ortho-alkylation of acetanilides;
arylation of cycloalkenes;
allylic acetoxylation;
oxidative coupling of alkenylstannanes;
lactonization of dienes by 1,4-functionation;
1,3,5-trienes;
cyclization of o-iodophenyl allyl ethers to benzofurans;
coupling of CH2CHSi(CH3)3 with vinyl iodides;
vinylation of cycloalkenes;
arylannelation of 1,3-dienes;
coupling of ArI and unsaturated epoxides;
bicyclic acetals;
1,4-additions to1,3-dienes;
didehydroamino acids;
cyclopentenones from carbohydrates;
3-arylcycloalkenes;
coupling of vinyl halides with allylic alcohols;
cyclization of 4,6- and 5,7-dieneamides;
oxaspirocyclic addition to 1,3-dienes;
RCH2CHO RCHCHOCH3 RCHCHCHO;
heck cyclization;
heck-type coupling of allylic alcohols and enol triflates;
coupling of vinyl halides with allyl alcohols;
arylation of allylic alcohols;
hydroacetoxylation of 2-alkynoates;
three-component coupling of alkenes;
heck reaction;
suzuki, stille, and related couplings;
reductive acylation and transesterification;
2-benzenesulfenyl-1,3-dienes;
allylic oxidation;
1,4-difunctionalization of 1,3-dienes;
cycloisomerization of enynes;
heck reaction;
arylation with onium salts;
suzuki couplings;
carboxylation;
addition to multiple bonds;
oxidation;
heck reaction and other couplings;
addition to multiple bonds;
dehydrogenation of carbonyl compounds;
indoles;
cyclopropanation;
enol ethers;
coupling reactions;
reactions of alkynes;
carbonyl compounds;
miscellaneous reactions;
hydroarylation;
carboxylation;
rearrangement-coupling;
conjugate addition;
coupling reactions;
redox reactions;
vinyl glycosides;
cyclizations;
additions;
allylic displacements;
cyclopropanation;
coupling reactions;
addition reactions;
cyclization reactions;
cyclopentadienone acetals;
oxidation;
ketone synthesis;
racemization;
transannular reaction;
coupling reactions;
oxidation;
aryl ketones;
reaction with ArNCl2;
halogenation;
reduction;
coupling reactions;
cyclization;
halogenation
read more
Chat with Paper
AI Agents for this Paper
Find similar papers on Google Scholar, PubMed and Arxiv
Write a critical review of this paper
Analyze citations of this paper to find unaddressed research gaps
Citations
Catalytic C-H Functionalization Driven by CO as a Stoichiometric Reductant - Application to Carbazole Synthesis
TL;DR: A palladium-catalyzed regioselective C-H bond functionalization driven by CO as the stoichiometric reductant is described, which achieves good yields with use of palladium acetate and 70 psig of carbon monoxide at 140 degrees C.
Formamide as a Superior Nitrogen Nuclesphile in Palladium@) MediatedSynthesis of Imidazolidines
Roll A. T. M. van Benthem,Henk HiemrHa,Gema Rodr,W. Nice Speckamp +3 more
- 01 Jan 1994
TL;DR: In this article, the authors reported several Pd(OAcz catalyzed oxidative cyclixations in which different tethered nitrogen nucleophiles were converted into imidazdidiacs 3.
References
Pd(II) Acts Simultaneously as a Lewis Acid and as a Transition-Metal Catalyst: Synthesis of Cyclic Alkenyl Ethers from Acetylenic Aldehydes.
TL;DR: The reaction of carbon-tethered acetylenic aldehydes with alcohols in the presence of a catalytic amount of Pd(OAc)2 in 1,4-dioxane at room temperature gave the 5- or 6-membered acetal products in high yields as discussed by the authors.
136
Palladium(II)‐Catalyzed Intramolecular Diamination of Alkynes under Aerobic Oxidative Conditions: Catalytic Turnover of an Iodide Ion
Bo Yao,Qian Wang,Jieping Zhu +2 more
TL;DR: The title reaction proceeds efficiently with 1 mol % of palladium and gives tetrahydroquinolines in excellent enantioselectivities and can be regioselectively and enantiospecifically reduced to chiral tetrahYDrobenzoazepines.
134
Development of an enantiodivergent strategy for the total synthesis of (+)- and (-)-dragmacidin f from a single enantiomer of quinic Acid.
TL;DR: An enantiodivergent strategy for the total chemical synthesis of both (+)- and (-)-dragmacidin F beginning from a single enantiomer of quinic acid has been developed and successfully implemented.
133