Journal Article10.1016/J.CHEMGEO.2006.06.006
New sample preparation techniques for the determination of Si isotopic compositions using MC-ICPMS
TL;DR: In this article, a method for the separation and purification of Si from natural samples to improve the determination of isotope ratios has been presented, based on alkaline fusion followed by ion-exchange chromatography.
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About: This article is published in Chemical Geology. The article was published on 30 Nov 2006. The article focuses on the topics: Isotope fractionation & Matrix (chemical analysis).
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Citations
Silicon in the Earth's core.
TL;DR: It is concluded that Si was already incorporated as a light element in the Earth’s core before the Moon formed, consistent with the recent proposal that there was large-scale isotopic equilibration during the giant impact.
327
An inter-laboratory comparison of Si isotope reference materials
Ben C. Reynolds,J. Aggarwal,Luc André,Douglas C. Baxter,Charlotte P. Beucher,Mark A. Brzezinski,Emma Engström,Emma Engström,R. Bastian Georg,R. Bastian Georg,Magnus Land,Melanie J. Leng,Melanie J. Leng,Sophie Opfergelt,Ilia Rodushkin,Ilia Rodushkin,Hilary J. Sloane,Sander H. J. M. van den Boorn,Pieter Z. Vroon,Damien Cardinal +19 more
TL;DR: In this paper, three Si isotope materials have been used for an inter-laboratory comparison exercise to ensure reproducibility between international laboratories investigating natural si isotope variations using a variety of chemical preparation methods and mass spectrometric techniques.
265
Accurate and precise determination of isotopic ratios by MC-ICP-MS: a review.
TL;DR: This review examines "state-of-the-art" methodologies presented in the literature for achievement of precise and accurate determinations of isotope ratios by MC-ICP-MS.
258
Lithium, magnesium and silicon isotope behaviour accompanying weathering in a basaltic soil and pore water profile in Iceland
Philip A.E. Pogge von Strandmann,Philip A.E. Pogge von Strandmann,Sophie Opfergelt,Sophie Opfergelt,Yi-Jen Lai,Bergur Sigfússon,Sigurður R. Gislason,Kevin W. Burton,Kevin W. Burton +8 more
TL;DR: In this article, the authors present lithium, magnesium and silicon isotope ratios from pore waters and soils from a well-characterised Histic Andosol in south-west Iceland.
222
Silicon isotope variations accompanying basalt weathering in Iceland
TL;DR: In this article, the Si isotope compositions of twenty rivers from across Iceland were used to provide interference-free 30Si/28Si ratios with an average limiting precision of ± 0.04 δ30Si.
213
References
MAGIC : a sensitive and precise method for measuring dissolved phosphorus in aquatic environments
David M. Karl,Georgia Tien +1 more
TL;DR: A simple and straightforward method has been developed for the precise determination of nanomolar concentrations of soluble reactive phosphorus (SRP) and total dissolved phosphorus (TDP) in marine and freshwater environments as discussed by the authors.
Silicon-isotope composition of diatoms as an indicator of past oceanic change
TL;DR: In this article, the authors exploit the potential that variations in the ratio of 30Si to 28Si in sedimentary opal may provide information on past silicon cycling that is unbiased by opal dissolution.
Natural Variations in Isotopic Abundances of Silicon
TL;DR: In this article, the isotopic abundance ratio of silicon is measured in the range of 5.3 to 5.7 per mil, with isotopic abundances centrally distributed within the observed normal terrestrial range.
A first look at the distribution of the stable isotopes of silicon in natural waters
TL;DR: In this article, the first data on the distribution of the stable isotopes of silicon in marine and freshwater systems are reported, and the average δ30Si value of inputs of silicon to the ocean most likely falls between +0.9 to +1.0
Measurement of silicon stable isotope natural abundances via multicollector inductively coupled plasma mass spectrometry (MC‐ICP‐MS)
TL;DR: In this paper, the authors used inductively coupled plasma mass spectrometer (ICP-MS) for silicon isotope ratio variations (δ29Si and δ30Si) analysis.
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