Journal Article10.1021/CR990119U
New polymer synthesis by nitroxide mediated living radical polymerizations.
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About: This article is published in Chemical Reviews. The article was published on 25 Oct 2001. The article focuses on the topics: Reversible addition−fragmentation chain-transfer polymerization & Chain transfer.
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Citations
First report of reversible addition–fragmentation chain transfer (RAFT) polymerisation in room temperature ionic liquids
TL;DR: The Reversible Addition-Fragmentation chain Transfer (RAFT) polymerisation of acrylate, methacrylates and styrene is reported for the first time in room temperature ionic liquids and shows a living character and lead to well-characterised polymers.
139
Effect of Electron Donors on the Radical Polymerization of Vinyl Acetate Mediated by [Co(acac)2]: Degenerative Transfer versus Reversible Homolytic Cleavage of an Organocobalt(III) Complex
TL;DR: It is proposed that the polymerization is controlled by the reversible homolytic cleavage of an organocobalt(III) dormant species in the presence of ED and the faster polymerization after the induction period in the absence of ED is due to a degenerative transfer process with the radicals produced by the continuous decomposition of the excess initiator.
139
Constructing star polymers via modular ligation strategies
Ozcan Altintas,Andrew P. Vogt,Christopher Barner-Kowollik,Umit Tunca +3 more
- 01 Jan 2012
TL;DR: In this paper, the modified Huisgen [3 + 2] dipolar copper catalyzed azide and alkyne cycloaddition (CuAAC) has been widely employed for macromolecular star synthesis.
139
Sequence-controlled multi-block copolymerization of acrylamides via aqueous SET-LRP at 0 °C
Fehaid Alsubaie,Athina Anastasaki,Paul Wilson,Paul Wilson,David M. Haddleton,David M. Haddleton +5 more
TL;DR: Aqueous single electron transfer living radical polymerization (SET-LRP) has been employed to synthesize multi-block homopolymers and copolymers of a range of acrylamide monomers as discussed by the authors.
139
References
Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization
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Preparation of polymers with controlled molecular architecture. A new convergent approach to dendritic macromolecules
TL;DR: In this article, a convergent growth approach to topological macromolecules based on dendritic fragments is described, where polyether dendric fragments are prepared by starting from what will become the periphery of the molecule and progressing inward.
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