Book Chapter10.1007/BFB0025902
Network formation by chain crosslinking photopolymerization and some applications in electronics
491
TL;DR: In this paper, the formation of densely crosslinked networks by chain crosslinking photopolymerization is discussed in relation to selected applications in the electronics industry, which make use of the high speed and the latitude to meet other requirements by variation of the chemical structure of the monomers.
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Abstract: The formation of densely crosslinked networks by chain crosslinking photopolymerization is discussed in relation to selected applications in the electronics industry. All of these applications make use of the high speed and of the latitude to meet other requirements by variation of the chemical structure of the monomers. The selection comprises:
1.
The coating of optical fibers;
2.
The replication of optical discs;
3.
The replication of aspherical lenses, used for laser read-out of these discs.
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Citations
Cationic photopolymerization of polyfunctional 1‐propenyl ether systems
Marco Sangermano,Giulio Malucelli,Roberta Maria Bongiovanni,Aldo Priola,Ulf Annby,Nicola Rehnberg +5 more
TL;DR: The thermal and dynamic-mechanical properties of the films obtained have been investigated and are correlated with the structure of the networks and to the mechanism of the curing reaction as discussed by the authors.
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Polyhydroxyacrylate–polyurethane semi-interpenetrating polymer networks
TL;DR: A series of semi-interpenetrating polymer networks based on a polyhydroxyacrylate of Bisphenol A and a polyurethane was synthesized by the simultaneous polymerization technique as discussed by the authors.
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Free-radical crosslinking copolymerization of acrylamide and N, N'-methylenebis acrylamide by used Ce(IV)/polyethylene glycol and Ce(IV)/diethylmalonate redox initiator systems
TL;DR: In this article, the critical conversion at the gel point shows a minimum at 6 mol at 6 m.% Bis when the monomer concentration was kept constant at 0.5 M and it was found that polymer formed with different Bis% are not dissolved in water, acetic acid, toluene or chloroform.
17
Use of acrylic functionalized (meth)acrylic cross-linked polymer microparticles in photopolymerized acrylic films
TL;DR: In this article, the effect of reactive microgels (reactive CPMs) on the thermo-mechanical properties of different photopolymerized thin films was studied.
17
Kinetic study of the photoinitiated polymerization of a liquid crystalline diacrylate monomer by d.s.c. in the isothermal mode
TL;DR: In this article, the photoinitiated polymerization of the liquid crystalline (LC) diacrylate monomer 1,4-(-2-methyl phenylene)-bis[4-(6-acryloyloxy-hexamethyleneoxy)benzoate] with T(k,n) = 85-degrees-C and T(i) = 118-degree-C, was studied by d.c.
17
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