Book Chapter10.1007/BFB0025902
Network formation by chain crosslinking photopolymerization and some applications in electronics
491
TL;DR: In this paper, the formation of densely crosslinked networks by chain crosslinking photopolymerization is discussed in relation to selected applications in the electronics industry, which make use of the high speed and the latitude to meet other requirements by variation of the chemical structure of the monomers.
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Abstract: The formation of densely crosslinked networks by chain crosslinking photopolymerization is discussed in relation to selected applications in the electronics industry. All of these applications make use of the high speed and of the latitude to meet other requirements by variation of the chemical structure of the monomers. The selection comprises:
1.
The coating of optical fibers;
2.
The replication of optical discs;
3.
The replication of aspherical lenses, used for laser read-out of these discs.
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Citations
Diffusion control in the kinetics of cross-linking
TL;DR: In this article, the effect of diffusion on the transition complex model is discussed on the basis of transition complex models, and the authors show that the observed deviations from the ideal branching process are also determined by static effects, such as volume exclusion, which make the rate constants dependent on the size and structure of the reacting molecules.
45
Kinetics and crystallization in pH-sensitive free-radical crosslinking polymerization of acrylic acid
TL;DR: In this paper, free-radical crosslinking polymerization and crystallization of acrylic acid (AAc) were investigated by shear storage modulus (G′) measurements in pH 2, as well as in pH 6 and pH 10, by varying the molar ratio of cross-linking agent (N,N′-methylene bis-acrylamide; MBAAm) to AAc.
45
Kinetic Behavior of Atom Transfer Radical Polymerization of Dimethacrylates
TL;DR: In this article, the reaction behavior and kinetics of the atom transfer radical polymerization (ATRP) of poly(ethylene glycol) dimethacrylates (PEGDMA) were studied with respect to polymerization rate, vinyl conversion and the development of a crosslinked network.
45
Photopolymerization of poly(tetramethylene ether) glycol diacrylates and properties of the obtained networks
TL;DR: In this paper, a series of poly(tetramethylene ether) glycol α,ω-diacrylates have been prepared from the corresponding hydroxy-terminated oligomers.
44
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Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function
Graham Williams,David C. Watts +1 more
TL;DR: In this article, the empirical dielectric decay function γ(t)= exp −(t/τ 0)β was transformed analytically to give the frequency dependent complex dielectrics constant if β is chosen to be 0.50 in the range log(ωτ0) > −0.5.
4.2K