Journal Article10.1016/J.COELEC.2020.05.006
Molecular design of ambipolar redox-active open-shell molecules: Principles and implementations
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TL;DR: In this paper, a mini-review highlights key structural features and provides guidelines for the molecular design of ambipolar redox-active frameworks, which are of interest for the fabrication of all-organic "poleless" batteries and semiconductors.
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About: This article is published in Current Opinion in Electrochemistry. The article was published on 01 Dec 2020. The article focuses on the topics: Ambipolar diffusion.
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Citations
Conjugated nitroxide radicals
Eugeny Viktorovich Tretyakov,Victor I. Ovcharenko,Alexander O. Terent'ev,Igor B. Krylov,Tatiana Vladimirovna Magdesieva,Dmitrii G. Mazhukin,Nina P. Gritsan +6 more
Abstract: In recent years, research dealing with organic paramagnetic compounds such as stable radicals and high-spin systems has been focused on applied aspects. Several key trends have formed in the application and, hence, in the function-oriented synthesis of organic radicals and polyradicals. This review addresses one of such trends in which the dominant role is played by so-called conjugated nitroxides. Their specific feature is the presence of any unsaturated moiety (C=C, C=N or C=O multiple bond; aromatic or heteroaromatic ring; fused polyaromatic system) adjacent to the nitroxide group. The achievements of the chemistry of conjugated nitroxides are presented, and their physicochemical properties, magneto-structural correlations and practical applications are discussed. The bibliography includes 641 references.
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Conjugated nitroxides
01 Mar 2022
TL;DR: In this article , a review of the chemistry of conjugated nitroxides is presented, and their physicochemical properties, magneto-structural correlations and practical applications are discussed.
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Blatter radical as a polymeric active material in organic batteries
TL;DR: In this article , the Blatter radical is applied in a cross-linked polymer to yield a stable and quickly chargeable electrode material for organic radical batteries, which exhibits excellent rate capabilities of up to 60 C, where it keeps 48% of the capacity at 1 C.
18
Electro-Oxidative C-N Bond Formation through Azolation of Indole Derivatives: An Access to 3-Substituent-2-(Azol-1-yl)indoles.
TL;DR: In this article, a practical protocol to synthesize 3-substituent-2-(azol-1-yl)indole derivatives has been developed via an electrochemical oxidative cross coupling process under mild conditions.
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TL;DR: In this article, the authors proposed a dynamic growth model where output is produced using two types of energy sources: fossil fuel and renewable energy, and they showed that adopting those policies should slow down the growth rate of cumulative emissions; but the outcome is contingent upon the carbon emission targets set for advanced countries, as distinct from those assigned to developing countries.
Ambipolar Small-Molecule:Polymer Blend Semiconductors for Solution-Processable Organic Field-Effect Transistors
Minji Kang,Hansu Hwang,Won-Tae Park,Dongyoon Khim,Jun-Seok Yeo,Yunseul Kim,Yeon-Ju Kim,Yong-Young Noh,Dong-Yu Kim +8 more
TL;DR: This work provides a one-step solution processing technique, which makes use of soluble ambipolar small molecules to form a thin-film semiconductor for application in high-performance OFETs.
Stable N- and N/S-Rich Heterocyclic Radicals: Synthesis and Applications
TL;DR: In this paper, the authors present a brief review of advances in heterocyclic neutral organic radicals that contain either an endocycic hydrazyl or thiazyl unit, focusing on new synthetic methods, physical properties and applications.