Journal Article10.1016/S0020-1693(99)00370-9
Molecular assembly of BINOLTi complexes into an active μ3-oxo titanium catalyst
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TL;DR: In this paper, a bridging tetranuclear titanium complex was obtained by exposing [Ti(OPri)2(BINOLato)] (2) to hydrated molecular sieves (MS) 4A, which is a precursor of active BINOLTi catalyst (1).
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About: This article is published in Inorganica Chimica Acta. The article was published on 15 Dec 1999. The article focuses on the topics: Catalysis & Titanium.
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Citations
New bulky chiral Lewis acid catalyst: 3,3′‐di(2‐mesitylethynyl)binaphthol–titanium(iv) complex
Kazuaki Ishihara,Jun Kobayashi,Kazuhiko Nakano,Hideaki Ishibashi,Hisashi Yamamoto,Hisashi Yamamoto +5 more
TL;DR: A new chiral Lewis acid catalyst 9 was prepared in situ from a 1:2 molar mixture of (R)-3,3'-di(2-mesitylethynyl)binaphthol and titanium(IV) isopropoxide to increase the enantioselectivity in the Diels-Alder reaction of methacrolein with cyclopentadiene.
8
Curtin–Hammett versus non-Curtin–Hammett frameworks in optimizing the enantioselective binolam/titanium(IV)-catalyzed cyanobenzoylation of aldehydes: Part 2
TL;DR: In this article, the authors presented a study supported by MICINN (Spain) through projects CTQ2007-62952/BQU, CTQ 2007-62771/B QUE, COBQU 2007-20387, COBE 2007-17339 and Consolider INGENIO 2010 CSD2007-00006.
Polyethylene Waxes: Catalytic Synthesis by Ti‐Biphenolates
TL;DR: In this paper, a catalytic system for polymerization of polyethylene (PE) was presented. But the PE waxes obtained with this catalytic scheme exhibit unique properties that have potential applications in surface coating and adhesive formulations.
7
References
•Book
Comprehensive asymmetric catalysis
Eric N. Jacobsen,Andreas Pfaltz,尚 山本 +2 more
- 01 Jan 1999
TL;DR: Ohkuma et al. as mentioned in this paper proposed an asymmetric Dihydroxylation process for carbon-Carbon double bonds and showed that it can be used for allylation of C=O.
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