Journal Article10.1002/ANIE.199116381
Methyltrioxorhenium as Catalyst for Olefin Oxidation
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About: This article is published in Angewandte Chemie. The article was published on 01 Dec 1991. The article focuses on the topics: Olefin fiber & Methylrhenium trioxide.
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Citations
Layered Transition Metal Carboxylates: Efficient Reusable Heterogeneous Catalyst for Epoxidation of Olefins
Rupam Sen,Susmita Bhunia,Dasarath Mal,Subratanath Koner,Yoshitaro Miyashita,Ken-ichi Okamoto +5 more
TL;DR: It is demonstrated that, instead of intercalating the metal complex into layers of the clay or LDH, layered transition metal carboxylates, [M(malonato)(H(2)O)(2)](n), can be used as a recyclable heterogeneous catalyst in olefin epoxidation reaction.
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Steps towards [(C5Me5)TcO3]: Novel synthesis of [(C5Me5)Tc(CO)3] from [{Tc(μ3−OH)(CO)3}4] and oxidation of [(C5Me5)M(CO)3] (M = Tc, Re) with Br2
Roger Alberto,Roger Schibli,A. Egli,Ulrich Abram,Sonja Abram,Thomas A. Kaden,P. August Schubiger +6 more
TL;DR: In this article, the tetranuclear complex [{Tc(μ3-OH)(CO)3}4] with HC5Me5 gave the important starting material for the tetrahedral 18e− M(III) complex.
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An improved methyltrioxorhenium-catalyzed epoxidation of alkenes with hydrogen peroxide
TL;DR: Methyltrioxorhenium (MTO)-catalyzed epoxidation of alkenes with H(2)O( 2) has been significantly improved by using 3-methylpyrazole as an additive.
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Bipyridine N,N′-Dioxide: A Felicitous Ligand for Methyltrioxorhenium-Catalyzed Epoxidation of Olefins with Hydrogen Peroxide
TL;DR: Methyltrioxorhenium-catalyzed oxidation of olefins with hydrogen peroxide in the presence of bipyridine N,N′-dioxide gave epoxides in high yields, with no sign of formation of hydrolyzed diols.
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