Journal Article10.1002/ADMA.201703663
Metal-Organic Frameworks as Platforms for Catalytic Applications.
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TL;DR: An overview of recent developments achieved in MOF catalysis, including heterogeneousCatalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided.
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Abstract: Metal-organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.
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Citations
Transformation of Metal‐Organic Frameworks into Stable Organic Frameworks with Inherited Skeletons and Catalytic Properties
Kai Chen,Chuan-De Wu +1 more
TL;DR: This work reports an effective strategy to transform fragile coordination bonds in MOFs into stable covalent organic bonds under mild annealing decarboxylative coupling reaction conditions, which results in highly stable organic framework materials.
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Synthesis and Applications of Metal-organic Frameworks and Graphene-Based Composites: A Review
TL;DR: A comprehensive review of the most recent advancements in metal-organic frameworks can be found in this article , where an effort has been made to summarize recent research in the synthesis of MOFs/graphene materials and their applications in varied fields including adsorption, gas separation, water splitting, dye and pollutant removal etc.
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Interface Engineering of Organic-Inorganic Heterojunctions with Enhanced Charge Transfer
Yizhou Wu,Yu Chen,Donglin Li,Dania Sajjad,Yixuan Chen,Yiying Sun,Shusong Liu,Jiafu Shi,Zhongyi Jiang +8 more
TL;DR: In this paper , a polyphenol-assisted assembly of titania (P25) and carbon nitride (CN) is constructed to eliminate non-ideal interfacial effects, and the uniform dispersion of P25 on CN enlarges the interfacial contacting area of 3.2-fold compared with random dispersion.
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Production of MOF Adsorbent Spheres and Comparison of Their Performance with Zeolite 13X in a Moving-Bed TSA Process for Postcombustion CO2 Capture
Giorgia Mondino,Aud I. Spjelkavik,Terje Didriksen,Shreenath Krishnamurthy,Ruth Elisabeth Stensrød,Carlos A. Grande,Lars O. Nord,Richard Blom +7 more
TL;DR: In this paper, a spray-granulation method with cross-bonded alginate as the binder was used to produce well-shaped 300-700 μm spheres of aggregated metal-organic framework CPO-27-Ni crystallites.
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Nanoengineered metal-organic framework architectures for adsorptive and photocatalytic mitigation of pharmaceuticals and pesticide from wastewater.
TL;DR: A comprehensive overview of the latest advances in metal-organic frameworks and their derivatives, focusing on the following aspects: synthesis and applications is provided in this paper , which summarizes the possible research challenges and directions for MOFs as catalysts applied to wastewater treatment in the future.
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