Journal Article10.1002/ADMA.201703663
Metal-Organic Frameworks as Platforms for Catalytic Applications.
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TL;DR: An overview of recent developments achieved in MOF catalysis, including heterogeneousCatalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided.
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Abstract: Metal-organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.
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Citations
Modifiers versus Channels: Creating Shape-Selective Catalysis of Metal Nanoparticles/Porous Nanomaterials
Fang Chuanzhen,Liwei Liu,Jiena Weng,Suoying Zhang,Xinglong Zhang,Zhen Ren,Yu Shen,Meng Fanchen,Bing Zheng,Sheng Li,Jiansheng Wu,Wenxiong Shi,Sungsik Lee,Weina Zhang,Fengwei Huo +14 more
TL;DR: A concept of creating shape selectivity in MNPs/porous-nanomaterials through intentionally poisoning certain MNPs using suitable modifiers is reported, promising for wide applications in selective catalytic systems.
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Visible light-driven efficient palladium catalyst turnover in oxidative transformations within confined frameworks
TL;DR: In this article , a new strategy for addressing Pd reoxidation problem by the fabrication of spatially proximate Ir III photocatalyst and Pd II catalyst into metal-organic framework (MOF), affording MOFs based Pd/photoredox catalysts UiO-67-Ir-PdX 2 (X = OAc, TFA), which are systematically evaluated using three representative Pd-catalyzed oxidation reactions.
A photosensitive metal–organic framework having a flower-like structure for effective visible light-driven photodegradation of rhodamine B
TL;DR: In this article, a method to synthesize flower-like porphyrin-based metal-organic frameworks (MOFs) using trifluoroacetic acid as a morphology control agent was proposed.
Porous two-dimension MnO2-C3N4/titanium phosphate nanocomposites as efficient photocatalsyts for CO oxidation and mechanisms
TL;DR: In this paper, a two-dimensional (2D) δ-MnO2-modified porous g-C3N4/micro-mesoporous titanium phosphate (MO-CN/TiP) nanocomposites have been controllably fabricated by a 2D solvothermal process.
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Confined Interface Transformation of Metal Organic Frameworks for Highly Efficient Oxygen Evolution Reaction
TL;DR: In this article , the real properties of a single MOF are highly dependent on the properties of the MOF's coordination structure and composition for various promising applications, and the authors propose a method to find the optimal MOF for each application.
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