Journal Article10.1002/ADMA.201703663
Metal-Organic Frameworks as Platforms for Catalytic Applications.
1.4K
TL;DR: An overview of recent developments achieved in MOF catalysis, including heterogeneousCatalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided.
read more
Abstract: Metal-organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.
read more
Chat with Paper
AI Agents for this Paper
Find similar papers on Google Scholar, PubMed and Arxiv
Write a critical review of this paper
Analyze citations of this paper to find unaddressed research gaps
Citations
Porous crystalline frameworks for thermocatalytic CO2 reduction: an emerging paradigm
Sunil Mehla,Ahmad Esmaielzadeh Kandjani,Ravichandar Babarao,Adam F. Lee,Selvakannan Periasamy,Karen Wilson,Seeram Ramakrishna,Suresh K. Bhargava +7 more
TL;DR: In this paper, a comprehensive and critical analysis of (thermal) CO2 reduction over catalysts derived from porous, crystalline frameworks, whose structural and chemical diversity offers unprecedented opportunities to regulate reactivity.
83
Versatile Functional Porous Cobalt-Nickel Phosphide-Carbon Cocatalyst Derived from a Metal-Organic Framework for Boosting the Photocatalytic Activity of Graphitic Carbon Nitride.
TL;DR: This work took the full advantage of MOF derivative for promoting the photocatalytic reaction activity, and provided a hopeful method for the design novel high-performance catalyst for the solar conversion.
83
Enabling photocatalytic hydrogen production over Fe-based MOFs by refining band structure with dye sensitization
A. P. Sadchikov,Shumin Li,Fan Wu,Golam Rabbani,Rongbin Lin,Leinonen, Jussi,Jin Wang,Chunxia Li,Zhengquan Li,Jun Jiang,Yujie Xiong +10 more
TL;DR: In this article, a combination of characterization techniques with theoretical simulation reveals that dye sensitization can effectively inject energetic electrons into Fe-MOFs and elevate their quasi-Fermi level under light irradiation, overcoming the surface overpotential for H2 production from water.
83
Progress, Mechanisms and Applications of Liquid‐Metal Catalyst Systems
TL;DR: Typical catalytic applications of LM systems discussed include the growth of graphene films/nanoribbons/carbon nanotube, photocatalytic degradation of CR or PFOA/splitting of H2 O/reduction of CO2, and catalytic reactions like butane or acetylene dehydrogenation, methanol steam reforming, and reduction of potassium ferricyanide.
82
Current Progress of Electrocatalysts for Ammonia Synthesis Through Electrochemical Nitrogen Reduction Under Ambient Conditions.
Anmin Liu,Yanan Yang,Xuefeng Ren,Qidong Zhao,Mengfan Gao,Weixin Guan,Fanning Meng,Liguo Gao,Qiyue Yang,Xingyou Liang,Tingli Ma,Tingli Ma +11 more
TL;DR: The design of high-performance electrocatalysts with the suppression of the HER for N2 reduction to NH3 under ambient condition is a crucial consideration for the development of Electrocatalytic NH3 synthesis with high FE and NH3 production rate.
82
References
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
7.7K
Metal–Organic Framework Materials as Chemical Sensors
Lauren E. Kreno,Kirsty Leong,Omar K. Farha,Mark D. Allendorf,Richard P. Van Duyne,Joseph T. Hupp +5 more
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
6.7K
Luminescent metal–organic frameworks for chemical sensing and explosive detection
TL;DR: This review intends to provide an update of work published since then and focuses on the photoluminescence properties of MOFs and their possible utility in chemical and biological sensing and detection.
3.9K
Metal-organic frameworks in biomedicine.
Patricia Horcajada,Ruxandra Gref,Tarek Baati,Phoebe K. Allan,Guillaume Maurin,Patrick Couvreur,Gérard Férey,Russell E. Morris,Christian Serre +8 more
TL;DR: Metal Organic Frameworks in Biomedicine Patricia Horcajada, Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre.
3.8K